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Titlebook: Chemical Science of π-Electron Systems; Takeshi Akasaka,Atsuhiro Osuka,Yoshio Aso Book 2015 Springer Japan 2015 Biomolecules.Carbon Nanotu

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Planar Cyclooctatetraenes and Related Ring Systems: Antiaromaticity and Applications, which is expected to be useful for various applications. In this chapter, the syntheses, antiaromaticity, and optical and electronic applications of planar COTs and related ring systems are reviewed.
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Dibenzopentalenes and Related Compoundsre, it was employed as a p-type material for organic heterojunction photovoltaic cells. The results indicate that π-extended pentalenes would serve as a good platform for materials applicable to organic electronics.
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Chiral Sumanene, Triazasumanene, and Related Buckybowlsic method under mild conditions, amenable enough to control the chirality, the reactivity of heteroatom, and high strain of bowl structure. As one of intrinsic properties of curved π-electron system, the first stereoelectronic effect of bowl-shaped π-electron system controlling the conformation of substituted sumanene is also described.
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Möbius Aromatic and Antiaromatic Expanded Porphyrinss dependent upon temperature and solvent polarity. Regioselective peripheral functionalizations of Möbius aromatic expanded porphyrins have been also developed. Möbius aromatic and antiaromatic expanded porphyrins display optical and electronic properties that are analogous to those of usual aromatic and antiaromatic porphyrinoids, respectively.
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