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Titlebook: Chemical Kinetics and Transport; Peter C. Jordan Book 1979 Springer Science+Business Media New York 1979 Atom.Diffusion.catalysis.chemical

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书目名称Chemical Kinetics and Transport
编辑Peter C. Jordan
视频video
图书封面Titlebook: Chemical Kinetics and Transport;  Peter C. Jordan Book 1979 Springer Science+Business Media New York 1979 Atom.Diffusion.catalysis.chemical
描述This book began as a program of self-education. While teaching under­ graduate physical chemistry, I became progressively more dissatisfied with my approach to chemical kinetics. The solution to my problem was to write a detailed set of lecture notes which covered more material, in greater depth, than could be presented in undergraduate physical chemistry. These notes are the foundation upon which this book is built. My background led me to view chemical kinetics as closely related to transport phenomena. While the relationship of these topics is well known, it is often ignored, except for brief discussions of irreversible thermody­ namics. In fact, the physics underlying such apparently dissimilar processes as reaction and energy transfer is not so very different. The intermolecular potential is to transport what the potential-energy surface is to reactivity. Instead of beginning the sections devoted to chemical kinetics with a discussion of various theories, I have chosen to treat phenomenology and mechanism first. In this way the essential unity of kinetic arguments, whether applied to gas-phase or solution-phase reaction, can be emphasized. Theories of rate constants and of che
出版日期Book 1979
关键词Atom; Diffusion; catalysis; chemical reaction; electrolyte; isotope; kinetics; photochemistry; physical chem
版次1
doihttps://doi.org/10.1007/978-1-4615-9098-9
isbn_softcover978-1-4615-9100-9
isbn_ebook978-1-4615-9098-9
copyrightSpringer Science+Business Media New York 1979
The information of publication is updating

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https://doi.org/10.1007/978-1-349-17975-6react, and recombine. This is done by constructing mechanistic models consistent with the phenomenological rate laws. Such mechanisms are rarely unique and guidelines are needed to construct them. The fundamental ground rule is simplicity. With this principle it becomes possible to choose between co
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Seeing-as and Religious Experience, must be run at high temperature or progress is imperceptible. Moreover, thermal activation is quite undiscriminating. Energy is partitioned among the various internal degrees of freedom of the reactants according to a Boltzmann distribution. There is no procedure to concentrate the energy of the re
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Problems of Religious Pluralismly. Naturally this was not always possible. Competition, reverse reaction, consecutive reaction, and inhibition all complicated the analyses. However, by limiting consideration to systems for which the steady-state assumption is appropriate, reasonably simple portraits of reaction could be drawn.
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In Defence of Religious Pluralism, only accounts for the overall phenomenology. The mechanism provides a model for the basic steps in the reaction. The molecular properties which determine whether or not reaction occurs can only be inferred from other chemical knowledge. Our previous discussion leads to only two very general, and ha
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