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Titlebook: Chemical Bonds Outside Metal Surfaces; Norman H. March Book 1986 Plenum Press, New York 1986 cluster.collision.crystal.diatomic molecule.e

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https://doi.org/10.1007/978-1-4613-2117-0cluster; collision; crystal; diatomic molecule; elastic scattering; hydrogen atom; modeling; molecule; neutr
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978-1-4612-9252-4Plenum Press, New York 1986
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Jan Machacek,Aleksa Vukotic,Jessica DittIn this chapter, the processes underlying molecular desorption from metal surfaces will be discussed in some detail. Three areas will be dealt with:
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Conformation and Electronic Structure of Polyatomic Molecules,here is obviously molecular conformation. Does benzene remain planar hexagonal on a particular face of tungsten? Is the water H—O—H angle changed from its free-space value when chemisorbed on ruthenium?. How does ethene behave on noble and transition metals?
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Catalysis,i.. These authors point out that the word “catalyst” was invented by Berzelius.to describe the property of certain substances which facilitate chemical change without being consumed during the reaction. Catalysts aid the attainment of chemical equilibrium by reducing the potential-energy barriers in the reaction path.
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Diatomic Molecules,his chapter, we shall be concerned primarily with the effect of the proximity of a planar metal surface on the binding energy of a diatomic molecule. Of course, it is clear that when the charge clouds of metal and molecule overlap strongly, then significant perturbations of the molecular valence ele
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