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Titlebook: Charge Transfer Reactions in Electrochemical and Chemical Processes; L. I. Krishtalik Book 1986 Consultants Bureau, New York 1986 Atom.Ion

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书目名称Charge Transfer Reactions in Electrochemical and Chemical Processes
编辑L. I. Krishtalik
视频video
图书封面Titlebook: Charge Transfer Reactions in Electrochemical and Chemical Processes;  L. I. Krishtalik Book 1986 Consultants Bureau, New York 1986 Atom.Ion
描述The mechanism of an elementary act is undoubtedly one of the most fundamental problems of chemical and, in particular, electro­ chemical kinetics. Although this problem has fascinated scientists for quite a long time, it was only in the late fifties and early sixties that it began to be actively investigated for charge transfer reactions. Owing to the development of new methods in the analysis of this problem, significant advancements were made in theoretical as well as experimental studies. These investigations showed that the physical mechanism of charge transfer in all processes including heterogeneous electrochemical and homogeneous chemical and bio­ chemical processes is basically the same. Hence, the results ob­ tained in the field of electrochemical kinetics are relevant to the understanding of homogeneous chemical reactions as well. This book endeavors to summarize the results of investigations carried out during the last two decades. It is based on the author‘s monograph "Electrode Reactions: The Mechanism of an Elementary Act" (Nauka, 1979). As compared to the first version, the book has been considerably revised and enlarged not only to include a large body of data publi
出版日期Book 1986
关键词Atom; Ion; chemical reaction; electrochemical kinetics; isotope; kinetics; metals; overpotential; polarizati
版次1
doihttps://doi.org/10.1007/978-1-4684-8718-3
isbn_softcover978-1-4684-8720-6
isbn_ebook978-1-4684-8718-3
copyrightConsultants Bureau, New York 1986
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Kinetics of Homogeneous and Enzymatic Reactions Involving Charge Transfer,greement with the predictions of the reorganization model, and in contradiction to the bond stretching model. The latter model, however, has so far been used to explain the main features of the kinetic isotope effect in homogeneous proton transfer reactions[256,443].
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Discharge of Heavy Ions. Quasibarrierless and Quasiactivationless Processes,. The activation energy will be determined by the distance from the minimum of the potential energy surface for the initial state to the saddle point on the line of intersection of this surface with the surface corresponding to the final state. This saddle point is characterized by the coordinates q*, R*, and the energy U*.
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