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Titlebook: Charge Transfer Processes in Condensed Media; Jens Ulstrup Textbook 1979 Springer-Verlag Berlin Heidelberg 1979 Atom.Chemical reaction.Kon

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书目名称Charge Transfer Processes in Condensed Media
编辑Jens Ulstrup
视频video
丛书名称Lecture Notes in Chemistry
图书封面Titlebook: Charge Transfer Processes in Condensed Media;  Jens Ulstrup Textbook 1979 Springer-Verlag Berlin Heidelberg 1979 Atom.Chemical reaction.Kon
描述Molecules in liquid and solid media are exposed to strong inter­ action forces from the surrounding medium. The formulation of a comprehensive theory of chemical processes in condensed media is consequently an elaborate task involving concepts from several areas of the natural sciences. Within the las~ two and a half decades very notable results towards the formulation of a ‘unified‘ quantum mechanical theory of such processes have in fact been achieved, and by the variety of physical, chemical, and biological processes which can be suitably covered by this framework, the new theory represents an adequate alternative to the transition state theory. The present work has a two-fold purpose. Firstly, to provide a reasonably organized exposition of some basic aspects of these developments. This part emphasizes the fundamental similarities between chemical and other kinds of radiationless processes and includes the derivation of the most important rate expressions without resorting to involved mathematical techniques. The s- ond major purpose is to illustrate the ‘unified‘ character of the rate theory by analysis of a considerable amount of expe- mental data from both ‘conventional‘ kin
出版日期Textbook 1979
关键词Atom; Chemical reaction; Kondensat; Ladungsaustauschreaktion; hydrogen; kinetics; metals; molecule; reaction
版次1
doihttps://doi.org/10.1007/978-3-642-93116-1
isbn_softcover978-3-540-09520-0
isbn_ebook978-3-642-93116-1Series ISSN 0342-4901 Series E-ISSN 2192-6603
issn_series 0342-4901
copyrightSpringer-Verlag Berlin Heidelberg 1979
The information of publication is updating

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Quantum Mechanical Formulation of Rate Theory,n which arises from interactions which were not included in the zero order Hamiltonians. Considering at first the former approach we notice that the sequence of events in chemical reactions between mobile species can be divided in three stages (33,94). Firstly, in the ‘infinitely remote’ past the re
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Application of the Rate Theory to Biological Systems,6). It is therefore of substantial interest to investigate to what extent the theory of elementary rate processes is applicable to biological systems. The systems where the ET chains have been resolved with a reasonable certainty into elementary steps is, however, restricted to ET in the mitochondri
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Multiphonon Representation of Continuous Media,cently become possible, by the invention of new high-pressure mass spectrometric. and flow techniques(123). The results are so far of a semiquantitative nature and refer only to proton transfer reactions. Less direct routes to the study of solvation effects requiring an elaborate theoretical framework must therefore be adopted.
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