Titlebook: Catalytic Reductive Carbonylation of Organic Nitro Compounds; Sergio Cenini,Fabio Ragaini Book 1997 Springer Science+Business Media Dordre

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0920-4652 re the academic interests (mechanism of the reactions, isolation of the intermediates in the catalytic cycles, synthesis of model compounds and so on) can find a lot of opportunities.978-90-481-4766-3978-94-017-0986-6Series ISSN 0920-4652 Series E-ISSN 2215-180X

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Angela N. Gist-Mackey,Hannah Oliha-Donaldson[4]. Note also that Fe(CO). is now known to be a selective catalyst for the reduction of nitrobenzene to azobenzene ([5], see also Chapter 4), although this fact was not known yet when the original report on the “uncatalysed” reaction was published.

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Bound(less): Re-storying Entrepreneurship low cost process, there has recently been an increasing interest in deeply investigating the potential utility of the catalytic carbonylation of organic nitro compounds in the synthesis of fine chemicals such as heterocycles. The assumption is that the synthesis of such expensive compounds, which i

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https://doi.org/10.1007/978-3-031-23236-7igh-pressure processes are related, which is rarely the case, the conclusions obtained in these studies should be looked at with caution. As we will see later, this problem is particularly relevant in the cases in which cluster precursors such as Ru.(CO). are used.

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Catalytic Reductive Carbonylation of Organic Nitro Compounds

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Synthesis of Isocyanates,al/mol can be calculated assuming ΔH. . = − 16.1 KcaUmol for PhNCO. [1]. Of course, the carbonylation of a dinitro derivative is an even more exothermic reaction (ΔH° = − 228 Kcal/mol for 2,4-dinitrotoluene to give 2,4-toluenediisocyanate [2]). However, in the absence of a catalyst, this reaction re

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Synthesis of Other Non-Cyclic Compounds,with transition metal complexes in their aci form [1]. Thus their reactivity is seldom comparable to the one shown by aromatic nitro derivatives. The catalytic synthesis of oximes by carbonylation of nitroalkanes is a rare example not only of their use in this type of catalysis, but also of the form

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Synthesis of Heterocycles,respect to the classical phosgene route. However, this is true if we consider only the cost of the reagents and the complexity of the equipment required by the two alternative routes. We are now living in a time in which environmentally friendly processes are required and, when evaluating alternativ