Titlebook: Catalytic Carbonylation Reactions; Matthias Beller Book 2006 Springer-Verlag Berlin Heidelberg 2006 Organometallic chemistry.Pauson–Khand

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Carbonylation of Ethene in Methanol Catalysed by Cationic Phosphine Complexes of Pd(II): from Polyk ligandon both the rate and the selectivity is delineated. In particular, it is shown that the catalytic activitycan be finely tuned by varying the electronic, bite angle and steric bulk properties of the ligand and that,within a series of related ligands, the selectivity mainly depends on the steric bulk.

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,The Pauson–Khand Reaction,oaches were established and the reactionhas been applied as a key step in various total syntheses. Recent work has also focused on the developmentof CO-free conditions, incorporating transfer carbonylation reactions. This review attempts to cover themost important developments in this area.

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Matthias BellerEach volume of Topics in Organometallic Chemistry provides the broad scientific readership with a comprehensive summary and critical overview of a specific topic in organometallic chemistry..Research

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978-3-642-06955-0Springer-Verlag Berlin Heidelberg 2006