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Titlebook: Catalytic Activation of Dioxygen by Metal Complexes; László I. Simándi Book 1992 Springer Science+Business Media Dordrecht 1992 Ion.cataly

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发表于 2025-3-21 19:49:26 | 显示全部楼层 |阅读模式
书目名称Catalytic Activation of Dioxygen by Metal Complexes
编辑László I. Simándi
视频video
丛书名称Catalysis by Metal Complexes
图书封面Titlebook: Catalytic Activation of Dioxygen by Metal Complexes;  László I. Simándi Book 1992 Springer Science+Business Media Dordrecht 1992 Ion.cataly
描述The activation of dioxygen by metal ions has both syntheticpotential and biological relevance. Dioxygen is the cleanest oxidantfor use in emission-free technologies to minimize pollution of theenvironment. The book gives a survey of those catalyst systems basedon metal complexes which have been discovered and studied in the lastdecade. They activate molecular oxygen and effect the oxidation ofvarious organic compounds under mild conditions. Much of the recentprogress is due to a search for biomimetic catalysts that wouldduplicate the action of metalloenzymes. Mechanistic aspects areemphasized throughout the book. An introductonary chapter reviews thechemistry of transition metal dioxygen complexes, which are usuallythe active intermediates in the catalytic reactions discussed.Separate chapters are devoted to oxidation of saturated, unsaturatedand aromatic hydrocarbons, phenols, catechols, oxo-compounds,phosphorus, sulfur and nitrogen compounds. .
出版日期Book 1992
关键词Ion; catalyst; iron; metals; oxygen; transition metal
版次1
doihttps://doi.org/10.1007/978-94-011-2850-6
isbn_softcover978-94-010-5265-8
isbn_ebook978-94-011-2850-6Series ISSN 0920-4652 Series E-ISSN 2215-180X
issn_series 0920-4652
copyrightSpringer Science+Business Media Dordrecht 1992
The information of publication is updating

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Catalytic Oxidation of Saturated Hydrocarbons with O2,dant is one of the most challenging and promising objectives of modern catalysis science. The development of efficient catalyst systems applicable in industrial practice would help to minimize pollution of the environment by chemical industries. Catalytic oxidation processes based on molecular oxyge
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Catalytic Oxidation of Alkenes with O2,e only considering liquid phase processes catalyzed by transition metal ions or complexes typically below 100–150 C. Many of these homogeneous catalytic reactions occur at or around room temperature. In addition to a single solvent containing the dissolved catalyst complex, phase-transfer conditions
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Catalytic Hydroxylation of Aromatic Hydrocarbons with O2,l substrate added to a metal complex — dioxygen system, or may be part of a ligand coordinated to the metal ion within the catalyst complex. Aromatic side-chain oxidations are treated in the sections for alkane, alkene or alkyne oxidation, depending on the substituent.
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Oxidation of Sulfur Compounds,red in petrochemical industry. Elimination of the foul odor arising from thiols (mercaptans) contained in some oils (“sweetening”) is mostly carried out by oxidation of thiols to disulfides. The oxidation of sulfur salts is also of practical importance in the processing of sulfide ores and handling
发表于 2025-3-23 01:31:31 | 显示全部楼层
Dioxygen Complexes, of man’s industrial activities. Free radical reactions with dioxygen are responsible for the generation of large amounts of heat and the appearance of flame. Selectivity is nonexistent in these spontaneous, high temperature processes.
发表于 2025-3-23 06:41:04 | 显示全部楼层
Catalytic Hydroxylation of Aromatic Hydrocarbons with O2,l substrate added to a metal complex — dioxygen system, or may be part of a ligand coordinated to the metal ion within the catalyst complex. Aromatic side-chain oxidations are treated in the sections for alkane, alkene or alkyne oxidation, depending on the substituent.
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