Titlebook: Catalysis in Chemistry and Biochemistry Theory and Experiment; Proceedings of the T Bernard Pullman Conference proceedings 1979 D. Reidel P

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The Macromolecular Electrostatic effect in Biochemical Reactivity of the Nucleic Acids,e work of Hayes and Kollman on carboxypeptidase A [1][2], in the work of Warshel on lysozyme [3][4], in the work of Van Duijnen on the role of the a-helix dipole on the reactional properties of proteins, in particular papain [5] [6] etc. (For general comments see also [7])- The different authors dif

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Studies on the Mechanism of Catalysis by Thiamin: Progress and Problems,methods: (a) disappearance of the signal of (C-2)H in D.O due to H—D exchange; (b) broadening of the (C-2)H signal in H.O solution due to H—H exchange. Rates calculated from the latter method are approximately two orders of magnitude larger than those from H—D exchange.

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Probing the Mechanism of Binding of the Thiamin Pyrophosphate Co-enzyme on Yeast Pyruvate Decarboxyancement in the fluorescence emission spectrum which enhancement can be subsequently quenched by the addition of thiamin pyrophosphate. The fluorescence data for the apoenzyme-Eu(III) binary complex indicate the existence of two types of binding sites with K.’s of 200 μm and (6±2) μm respectively. A

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A Personal History of Web Search,methods: (a) disappearance of the signal of (C-2)H in D.O due to H—D exchange; (b) broadening of the (C-2)H signal in H.O solution due to H—H exchange. Rates calculated from the latter method are approximately two orders of magnitude larger than those from H—D exchange.

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Dynamic and Statistical Aspects of Enzyme Action,and statistical aspects. From the more complete description several new proposals about enzyme action, control and evolution are advanced: some general theoretical and experimental approaches for testing these suggestions are indicated. The arguments require reference to the statistical nature of th