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Titlebook: Catalysis by Unique Metal Ion Structures in Solid Matrices; From Science to Appl Gabriele Centi,Blanka Wichterlová,Alexis T. Bell Book 2001

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发表于 2025-3-21 19:58:55 | 显示全部楼层 |阅读模式
书目名称Catalysis by Unique Metal Ion Structures in Solid Matrices
副标题From Science to Appl
编辑Gabriele Centi,Blanka Wichterlová,Alexis T. Bell
视频video
丛书名称NATO Science Series II: Mathematics, Physics and Chemistry
图书封面Titlebook: Catalysis by Unique Metal Ion Structures in Solid Matrices; From Science to Appl Gabriele Centi,Blanka Wichterlová,Alexis T. Bell Book 2001
描述Atomically dispersed metal cations and small polyatomiccationic structures co-ordinated to the surface of porous matricesexhibit different properties from the same cationic species containedin a bulk oxide or supported on amorphous carriers. This subject istreated to an extensive review, showing how an understanding of it isessential to the development of a new generation of solid catalysts.There are also exciting opportunities to shape the catalyticproperties of the transition metal cations in microporous andmesoporous matrices. .The book covers both theoretical and experimental aspects, includingthe distribution of framework Al atoms in Si-rich zeolites,distribution and siting of charge-exchanged metal cations, electronic,adsorptive and catalytic properties of metal cations, and correlationof metal cation structure and siting with catalytic activity.
出版日期Book 2001
关键词ITIES; Ion; catalysis; catalyst; hydrogen; metals; oxygen; photocatalysis; structure; transition metal; zeolit
版次1
doihttps://doi.org/10.1007/978-94-010-0782-5
isbn_softcover978-0-7923-6875-5
isbn_ebook978-94-010-0782-5Series ISSN 1568-2609
issn_series 1568-2609
copyrightSpringer Science+Business Media Dordrecht 2001
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发表于 2025-3-21 23:11:37 | 显示全部楼层
General Optimal Control Problemility is defined with reference to either reduction to metallic particles or demetallation to form metal oxide particles. The siting requirements and stability of binuclear cations, viz. [M-O-M]., are also examined.
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https://doi.org/10.1007/978-3-030-91059-4n numbers for Co/FER, MFI and MOR samples and thus enabled to characterize the average Co ion site in the zeolite framework. The results also indicated, in agreement with FTIR spectra, that Co ions deform the zeolite support to reach an optimal bonding with the framework.
发表于 2025-3-22 12:47:57 | 显示全部楼层
The Limitless Horizons of Space Art,luminescence spectra are assigned to these types of sites. Cu. ions on the channel intersection (type I) bind NO stronger than naked Cu. ions and it is suggested that these sites are catalytically active. A possible explanation of the higher catalytic activity of Cu/ZSM-5 compared to Cu/FER is proposed.
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Sílvia Faria,José Lima,Paulo Costathe proton exchanges with metal cation. Ti-MCM- 41 was the most active among the metal ion-planted MCM-41 for catalytic asymmetric oxidation of sulphide with hydrogen peroxide in the presence of optically active tartaric acid in dichloromethane.
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Ion Exchange of Non-Framework Cations in Zeolites for Catalysis,l it, we can use it to our advantage in catalyzing a number of reactions. A survey of the impact of ion exchange upon several reactions is provided. Comparisons are made with regard to activity and cation siting within the zeolite. Finally, a listing of opportunities for future research is provided.
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Mono- and Multinuclear Oxo-Cations in Zeolite Cavities,changed zeolite“. Binuclear oxo-ions, such as bipositive [Cu-O-Cu], [HO-Fe- O-Fe-OH], and [HO-Fe-O-O-Fe-OH] ions, in zeolite cavities are crucial in novel catalysts for NO. reduction and catalytic oscillation of N.O decomposition.
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