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Titlebook: Catalysis; Science and Technolo J. R. Anderson,M. Boudart Book 1991 Springer-Verlag Berlin Heidelberg 1991 Atom.Katalysator.Katalyse.cataly

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书目名称Catalysis
副标题Science and Technolo
编辑J. R. Anderson,M. Boudart
视频videohttp://file.papertrans.cn/223/222456/222456.mp4
丛书名称Catalysis
图书封面Titlebook: Catalysis; Science and Technolo J. R. Anderson,M. Boudart Book 1991 Springer-Verlag Berlin Heidelberg 1991 Atom.Katalysator.Katalyse.cataly
描述Our understanding of catalytic reactions exists at various levels which are mainly defined from detailed knowledge of reaction mechanism. When viewed in terms of the stoi­ chiometric reaction equation, most catalytic reactions are complex processes which occur via a sequence of elementary (i. e. irreducible) steps, and the elucidation ofthese elementary steps and the identification of a rate determining step (if one exists) constitutes the traditional approach to the problem of mechanism. The term "traditional" is not used here in a pejorative sense since mechanistic knowledge of this sort makes an important contribution to catalyst design, improvement, and optimization. This is the field which is discussed by Professor R. L. Burwell in Chapter 1 where the very wide range of useful approaches and techniques is made apparent, even when one is restricted to quasi-steady state conditions. Techniques which depend on observations under non­ steady state conditions (i. e. relaxation methods) have also been used in mechanistic studies, increasingly so in recent years. This topic is discussed in detail by Professor K. Tamaru in Chapter 2. At a deeper level of understanding, one may seek to
出版日期Book 1991
关键词Atom; Katalysator; Katalyse; catalysis; catalyst; complexity; energy; reactions
版次1
doihttps://doi.org/10.1007/978-3-642-75956-7
isbn_softcover978-3-642-75958-1
isbn_ebook978-3-642-75956-7Series ISSN 0175-9361
issn_series 0175-9361
copyrightSpringer-Verlag Berlin Heidelberg 1991
The information of publication is updating

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Dynamic Relaxation Methods in Heterogeneous Catalysis,on the details of the method, one may use the terms transient method or simply dynamic approach or, in some cases, isotope jump method (or transient tracing method) when labeled species are employed [1–4].
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Dynamics of Heterogeneously Catalyzed Reactions,ence of elementary steps that accomplishes the overall reaction. For example, the mechanism of CO oxidation on Pt may be written [2]:.Here we have assumed that CO is associatively and reversibly adsorbed and O. is dissociatively and irreversibly adsorbed at the reaction temperature. Both reactions o
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Book 1991echniques which depend on observations under non­ steady state conditions (i. e. relaxation methods) have also been used in mechanistic studies, increasingly so in recent years. This topic is discussed in detail by Professor K. Tamaru in Chapter 2. At a deeper level of understanding, one may seek to
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