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Titlebook: Carbohydrates; Synthesis, Mechanism Momcilo Miljkovic Book 2009 Springer-Verlag New York 2009 Carbohydrate.Chemistry.Glycoscience.Miljkovic

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发表于 2025-3-21 16:32:42 | 显示全部楼层 |阅读模式
书目名称Carbohydrates
副标题Synthesis, Mechanism
编辑Momcilo Miljkovic
视频video
概述Extensive references (in excess of 1,600) to the primary literature.Concentrates on important reactions, without esoteric topics.Includes supplementary material:
图书封面Titlebook: Carbohydrates; Synthesis, Mechanism Momcilo Miljkovic Book 2009 Springer-Verlag New York 2009 Carbohydrate.Chemistry.Glycoscience.Miljkovic
描述.All essential areas of basic synthetic carbohydrate chemistry are covered and appropriately described. In addition, this book explains the basic reaction mechanisms while taking into account modern concepts such as stereoelectronic principles..
出版日期Book 2009
关键词Carbohydrate; Chemistry; Glycoscience; Miljkovic; Natural products; Oxidation; Reaction mechanisms; natural
版次1
doihttps://doi.org/10.1007/978-0-387-92265-2
isbn_softcover978-1-4614-9825-4
isbn_ebook978-0-387-92265-2
copyrightSpringer-Verlag New York 2009
The information of publication is updating

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发表于 2025-3-21 23:39:15 | 显示全部楼层
https://doi.org/10.1007/978-0-387-92265-2Carbohydrate; Chemistry; Glycoscience; Miljkovic; Natural products; Oxidation; Reaction mechanisms; natural
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Nucleophilic Displacement and the Neighboring Group Participation,nal bipyramidal pentacovalent carbon transition state . and results in the inversion of configuration at the reacting carbon atom (the configuration of . vs. .) (Fig. 7.1); it usually follows the second-order kinetics.
发表于 2025-3-22 18:21:51 | 显示全部楼层
Oxidation of Monosaccharides,vatives from simple monosaccharides. As already mentioned in Chapter 5 the carbohydrates have three types of chemically distinct hydroxyl groups: (1) the primary hydroxyl groups which are always exocyclic and (2) two types of secondary hydroxyl groups: endo- and exocyclic hydroxyl groups.
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Synthesis of Polychiral Natural Products from Carbohydrates,s of macrolide antibiotics represents one such difficult problem. They consist of macrocyclic lactone rings with many hydroxylated and methylated chiral carbons. In addition to that the macrocyclic lactones (macrolides) are usually glycosylated with amino sugars.
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pplementary material: .All essential areas of basic synthetic carbohydrate chemistry are covered and appropriately described. In addition, this book explains the basic reaction mechanisms while taking into account modern concepts such as stereoelectronic principles..978-1-4614-9825-4978-0-387-92265-2
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