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Titlebook: Capture and Utilization of Carbon Dioxide with Polyethylene Glycol; Zhen-Zhen Yang,Qing-Wen Song,Liang-Nian He Book 2012 The Author(s) 201

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书目名称Capture and Utilization of Carbon Dioxide with Polyethylene Glycol
编辑Zhen-Zhen Yang,Qing-Wen Song,Liang-Nian He
视频videohttp://file.papertrans.cn/222/221507/221507.mp4
概述Provides updated advances on carbon dioxide chemistry in organic synthesis.Particularly shows PEG-promoted CO2 chemistry on the basis of understanding about the phase behavior of PEG/CO2 system.System
丛书名称SpringerBriefs in Molecular Science
图书封面Titlebook: Capture and Utilization of Carbon Dioxide with Polyethylene Glycol;  Zhen-Zhen Yang,Qing-Wen Song,Liang-Nian He Book 2012 The Author(s) 201
描述In this volume, Professor He and his coworkers summarize polyethylene glycol (PEG)-promoted CO2 chemistry on the basis of understanding about phase behavior of PEG/CO2 system and reaction mechanism at molecular level. As PEG could be utilized as a green replacement for organic solvents, phase-transfer catalyst, surfactant, support in various reaction systems, significantly promoting catalytic activity and recovering expensive metal catalysts, particularly regarded as a CO2-philic material, the authors focus on special applications of PEG in CO2 capture and utilization, including PEG-functionalized catalysts for efficient transformation of CO2 and PEG-functionalized absorbents for efficient CO2 capture. .Furthermore, they describe carbon capture and utilization strategy as an alternative approach to address the energy penalty problem in carbon capture and storage. .Interestingly, the authors also discuss PEG radical chemistry in dense CO2 as rather creative and unusual use of PEG,presumably serves as a reaction medium and a radical initiator for radical chemistry.
出版日期Book 2012
关键词Carbon Capture and Utilization; Carbon Dioxide Chemistry; Green Solvent; Green Synthetic Chemistry; PEG
版次1
doihttps://doi.org/10.1007/978-3-642-31268-7
isbn_softcover978-3-642-31267-0
isbn_ebook978-3-642-31268-7Series ISSN 2191-5407 Series E-ISSN 2191-5415
issn_series 2191-5407
copyrightThe Author(s) 2012
The information of publication is updating

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CO2 Capture with PEG,es (.) and PEG-functionalized liquid absorbents (.). Indeed, PEG could increase the solubility of CO. in the absorbent through chemical interactions, which is detected by in situ FT-IR under pressure.
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CO2 Capture, Activation, and Subsequent Conversion with PEG,an activated form of CO., as a feedstock, which renders the reaction system suitable for accomplishing chemical transformation of CO. under low pressure (ideally at 1 atm), and simultaneously getting rid of desorption step in CCU process. Indeed, activation of CO. through carbamate/alkyl carbonate f
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Capture and Utilization of Carbon Dioxide with Polyethylene Glycol
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2191-5407 blem in carbon capture and storage. .Interestingly, the authors also discuss PEG radical chemistry in dense CO2 as rather creative and unusual use of PEG,presumably serves as a reaction medium and a radical initiator for radical chemistry.978-3-642-31267-0978-3-642-31268-7Series ISSN 2191-5407 Series E-ISSN 2191-5415
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https://doi.org/10.1007/978-1-4020-5018-3d separation process. In this chapter, phase behavior of different PEG/CO. systems from 1.13–29.00 MPa CO. pressure at 313.15–348.15 K with PEG molecular weights (MWs) in the range of 200–35000 is discussed. Ternary systems such as CO./PEG/ethanol, CO./PEG/1-pentanol, CO./PEG/1-octanol, CO./PEG/1, 4
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https://doi.org/10.1007/978-1-4020-5018-3on reactions (.); PEG as surfactant for Aldol- and Mannich-type reactions (.); PEG as support for oxidation of alcohols, hydroformylation of olefins (.); and PEG as radical initiator for formylation of alcohols benzylic C=C cleavage reactions (.).
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