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Titlebook: Calixarenes and Beyond; Placido Neri,Jonathan L. Sessler,Mei-Xiang Wang Book 2016 Springer International Publishing Switzerland 2016 Calix

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Resorc[4]arenes as Preorganized Synthons for Surface Recognition and Host-Guest Chemistry,cation inside the cavities of ad hoc functionalized resorc[4]arenes, which yielded both complexes and covalent products. Finally, some recent intriguing resorc[4]arene architectures built up by olefin metathesis reaction occurring between side chains ending with vinylidene groups are presented.
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H. E. Klein,E. Rüther,J. Staedtx[.]arenes, and their structural characteristics. The synthetic methods available to obtain the macrocycles from simple starting materials have opened up opportunities for applications for these novel compounds.
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, Substitution of Calixarenes,t common ways to obtain these derivatives: step-by-step fragment condensations, the use of .-orienting groups or intramolecular ring closing of already .-substituted compounds, .-bromodienone route and direct mercuration reactions leading to useful intermediates for further transformations.
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Calix[6]azacryptand-Based Receptors,coordinating solvents). Their flexibility allows induced-fit processes and their hosting properties can be allosterically controlled by the addition of acids and bases. All these recognition properties are highly reminiscent of the binding processes operating in natural systems.
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A Chronology of Cavitands,t subsequent sections deal with velcrands and stereo-selective bridging to form deep-cavity cavitands. For all of the topics, the selected examples are given in chronological order to provide an over-view of the development of this fascinating field.
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