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Titlebook: Cage Metal Complexes; Clathrochelates Revi Yan Voloshin,Irina Belaya,Roland Krämer Book 2017 Springer International Publishing AG 2017 Cage

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发表于 2025-3-21 17:07:50 | 显示全部楼层 |阅读模式
书目名称Cage Metal Complexes
副标题Clathrochelates Revi
编辑Yan Voloshin,Irina Belaya,Roland Krämer
视频video
概述An exhaustive summary of clathrochelate cage metal complexes and their chemistry, summarizing synthesis and introducing reactivity and applications.Contains over 400 literature references, clearly rep
图书封面Titlebook: Cage Metal Complexes; Clathrochelates Revi Yan Voloshin,Irina Belaya,Roland Krämer Book 2017 Springer International Publishing AG 2017 Cage
描述.This fundamental book presents the most comprehensive summary of the current state in chemistry of cage metal complexes. After their previous book “The Encapsulation Phenomenon” (www.springer.com/978-3-319-27737-0) the authors in this book focus on the encapsulation of metal ions by different types of three-dimensional mono- and polynucleating caging ligands. Within these cage metal complexes, (metal) ions can be isolated from external factors...The book provides both a classification of the cage compounds and summaries of synthetic approaches. On that basis the authors then describe the unique chemical and physical properties and the resulting reactivity of the cage compounds, as well as practical and potential applications as potent topological drugs and prodrugs, antifibrillogenic agents, radiodiagnostic and radiotherapeutic compounds, paramagnetic probes, single-molecule magnets, electrocatalysts for hydrogen production, (photo)electronic devices, and many more..Readers will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented
出版日期Book 2017
关键词Cage compounds; Caging ligands; Cation encapsulation; Macrocyclic compounds; Clathrochelates; Paramagneti
版次1
doihttps://doi.org/10.1007/978-3-319-56420-3
isbn_softcover978-3-319-85910-1
isbn_ebook978-3-319-56420-3
copyrightSpringer International Publishing AG 2017
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General Considerations,e formation of a complex with an encapsulated metal ion in which (1) a three-dimensional cavity in its macropolycyclic ligand is present, and (2) the metal ion coordinates heteroatoms of this ligand within its cavity, isolating such encapsulated ion from the external factors.
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General Considerations,ule(s)] have been provided [1]. They include “(1) the presence of three-dimentional cavity in either covalent, or coordination, or supramolecular caging ligand (capsule) and (2) encapsulation of the above guest anion(s), cation(s) or neutral molecule(s), or their combination within this cavity . for
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Synthesis and Reactivity of Cage Metal Complexes,unique or uncommon chemical, physicochemical, and physical properties. Until publication of our first book on clathrochelate chemistry in 2002 [1], main synthetic approaches for preparation of various types of clathrochelates have included:
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Practical Applications of Cage Metal Complexes,summarized in this chapter are based on their unprecedented chemical robustness, unusual redox and magnetic properties of an encapsulation metal ion, and three-dimensional shape of these cage molecules as well as on special selectivity of their self-assembly reactions.
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Book 2017ectrocatalysts for hydrogen production, (photo)electronic devices, and many more..Readers will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented
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will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented 978-3-319-85910-1978-3-319-56420-3
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