Titlebook: Bioorganic Chemistry Frontiers; Hermann Dugas,Franz P. Schmidtchen Book 1993 Springer-Verlag Berlin Heidelberg 1993 Biochemie.Eisen.Organi

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Optical bistability in semiconductors,cific patterns of hydrogen bonding and the great basicity of the guanidine functional group allow it to play several key roles in recognition and catalysis. This chapter outlines recent findings of guanidinium groups in natural systems and advances in synthetic receptors that incorporate guanidinium

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Nathan P. Roehr,Nicolas C. PolferSupramolecular catalysis and reactivity represent major features of supramolecular chemistry. The design of selective molecular catalysts may reveal important factors contributing to enzymatic catalysis and provide synthetic reagents for specific chemical transformations.

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0938-7234 Overview: 978-3-642-78112-4978-3-642-78110-0Series ISSN 0938-7234

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978-3-642-78112-4Springer-Verlag Berlin Heidelberg 1993

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The Guanidinium Group: Its Biological Role and Synthetic Analogs,ins which possess essential arginine groups will be briefly introduced. Finally, several artificial receptors will be analyzed in terms of hydrogen bonding patterns and the ability to use the guanidinium functional group to specifically recognize, orient, and enhance the cleavage of phosphodiesters.

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