Titlebook: Accurate Structure Determination of Free Molecules; Jean Demaison,Natalja Vogt Book 2020 Springer Nature Switzerland AG 2020 Equilibrium S

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https://doi.org/10.1007/978-1-60327-161-5The rovibrational spectroscopy of the diatomic molecule is reviewed. The different structures are defined. The determination of the equilibrium structure is discussed as well as the influence of higher-order effects, including the breakdown of the Born–Oppenheimer approximation and the effect of the size of the nuclei.

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Arthrogryposis Multiplex Congenita,This chapter defines the different atomic radii and their use to predict a bond length. The valence-shell electron-pair repulsion (VSEPR) model and the ligand close-packing (LCP) model are reviewed. Finally, different empirical correlations are reported.

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Asphyxiating Thoracic Dystrophy,Databases containing information on molecular structure are reviewed. The database with numerical data on molecular geometry determined by high-resolution spectroscopy and electron diffraction in the gas phase (MOGADOC) is presented in detail.

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Atlas of Genetic Diagnosis and Counselingally examined. Then, the different ways to determine an equilibrium structure are described. A particular emphasis is put on the semiexperimental method that combines ground-state experimental rotational constants and computed ab initio rovibrational corrections. The accuracy of the different methods is discussed.

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