| 书目名称 | The Structure Dependent Energy of Organic Compounds | | 编辑 | Árpád Furka | | 视频video | | | 概述 | Describes an alternative thermochemical reference system that makes it possible to calculate the structure dependent energies for organic compounds, radicals, cations and anions.Includes calculated st | | 丛书名称 | SpringerBriefs in Molecular Science | | 图书封面 |  | | 描述 | This brief introduces readers to an alternative thermochemical reference system that makes it possible to use the heats of formation of organic compounds to deduce the energies that depend entirely on their structures, and which provides calculated values for most of the characteristic structures appearing in organic molecules. These structure-dependent energies are provided e.g. for selected compounds of normal and cyclic alkanes, open chain and cyclic olefins (including conjugated polyenes), alkynes, aromatic hydrocarbons and their substituted derivatives. The oxygen, sulfur and nitrogen derivatives of the above-mentioned compounds are also represented with calculated structure-dependent energies including alcohols, ethers, aldehydes and ketones, carboxylic acids, thiols, sulfides, amines, amides, heterocyclic compounds and others. Most organic reactions can be interpreted as the disappearance of certain structures and formation of others. If the structure-dependent energies are known, it can be shown how the disappearing and the newly formed structures contribute to the heat of reactions and to the driving forces. As experienced by the author, who pioneered the concept, structur | | 出版日期 | Book 2019 | | 关键词 | structure dependent energy; thermochemical reference system; relative enthalpies; heats of reactions; en | | 版次 | 1 | | doi | https://doi.org/10.1007/978-3-030-06004-6 | | isbn_softcover | 978-3-030-06003-9 | | isbn_ebook | 978-3-030-06004-6Series ISSN 2191-5407 Series E-ISSN 2191-5415 | | issn_series | 2191-5407 | | copyright | The Author(s), under exclusive license to Springer Nature Switzerland AG 2019 |
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发表于 2025-3-21 18:39:18
