书目名称 | Th Thorium | 副标题 | Compounds with Carbo | 编辑 | Kenneth W. Bagnall,Karl-Christian Buschbeck,Cornel | 视频video | | 丛书名称 | Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition | 图书封面 |  | 描述 | The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compounds of the type 4 ThAn· X B, where B is a neutral ligand. The complex equilibria of the Th + ion with C-containing complexing agents are treated in the ThD1 volume. A first look into this volume demonstrates that a very large number of ThlV complexes has 4 been prepared. This may be explained by the fact that the Th + ion is the largest tetravalent ion of the periodic table. Therefore, the preparation of complexes with, e. g. , multidentate ligands can give a well-established picture of the coordination number as a function of charge and ionic radius. However, there are very few modern and updated comprehensive treatments of such data. Many compounds described in this volume are characterized by no other means than analytical composition and IR spectra (whereby IR spectra of organic ThlV salts mostly give information only on the ligand). Besides thorium carbonate and carbonato complexes, which are relevant for the environmental behaviour of this radioactive element and some organic complexes like oxalates, which are used in the field | 出版日期 | Book 1988Latest edition | 关键词 | behavior; chemistry; element; environment; information; iron; spectra | 版次 | 8 | doi | https://doi.org/10.1007/978-3-662-06315-6 | isbn_softcover | 978-3-662-06317-0 | isbn_ebook | 978-3-662-06315-6 | copyright | Springer-Verlag Berlin Heidelberg 1988 |
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