Titlebook: Structural and Electronic Paradigms in Cluster Chemistry; D. M. P. Mingos Book 1997 Springer-Verlag Berlin Heidelberg 1997 Borane.Chemisch

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Structural and Electronic Paradigms in Cluster Chemistry978-3-540-68689-7Series ISSN 0081-5993 Series E-ISSN 1616-8550

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Structure and Bondinghttp://image.papertrans.cn/t/image/880068.jpg

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https://doi.org/10.1007/BFb0018028Borane; Chemische Bindung; Cluster; Valenzel; bonding; boranes; clusters; electron counting rules; nackte Cl

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Diverse naked clusters of the heavy main-group elements. Electronic regularities and analogies,he group 14 and 15 elements isolated from nonaqueous solvents and (2) numerous anionic clusters of particularly in and Tl found in “neat” alkali-hypo electronic, open-shell, and centered clusters and in networks are also described.

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Mathematical cluster chemistry, development of localised orbital and spherical harmonic methods are outlined and there is an introduction to Tensor Surface Harmonic Theory and Group Theory on a Spherical Shell. The inter-relationships between these approaches and their links with simple molecular orbital models, such as Hückel Th

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theta-waves

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,Clusters with interstitial atoms from the ,-block: How do Wade’s rules handle them?,titial atoms from the .-block. The discussion focuses on the classification of clusters using Wade‘s rules, and on their successes and failures which can be rationalized in terms of the relationship of a particular metal cluster to a deltahedral [B.H.]. anionic prototype cluster. The need to extend