Titlebook: Solution Behavior of Surfactants; Theoretical and Appl K. L. Mittal,E. J. Fendler Book 1982 Plenum Press, New York 1982 Action.ETA.Migratio

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Transition State Structure for the Reversible Hydration of 1, 3-Dichloroacetone in the Presence of Ae of bis-2-ethylhexyl sodium sulphosuccinate (Aerosol-OT or AOT) reversed micelles in hexane differ from those observed in aqueous dioxane. The transition state (TS) structure for the micellar reaction was probed by subjecting the reaction to a proton inventory study. The results show that the TS st

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Solubilization in Aqueous Micellar Solutions Studied by NMR-Methodson, orientation and mobility of the solubilized molecules. Assotiated changes in size and shape of the micelles can also be monitored. .H chemical shift measurements have been performed to determine the localization of aromatic and aliphatic solubilizates. It has been found .. that in CTAB-micelles

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Reactive Counterion Surfactantsirst order rate constants will increase with surfactant concentration until the substrate is fully micellar bound and will then become constant. This predicted behavior is observed for nucleophilic addition or substitution by cyanide or bromide ion and for acetal hydrolysis in micellized alkanesulfo

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Photon Correlation Spectroscopy of Inverted Micellar Aggregates of AOT in Heptaneosity and density measurements indicate that solutions of AOT in heptane have higher viscosities than predicted by the hard sphere theories. Photon correlation spectroscopy results give a concentration and solvent independent hydroynamic radius of 16A° and an aggregation number of 16 for inverse micelles without added water.