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Titlebook: Silicon Containing Copolymers; Sahar Amiri,Mohammad Ali Semsarzadeh,Sanam Amiri Book 2014 The Author(s) 2014 Block Copolymers.Cobalt Media

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发表于 2025-3-21 18:33:32 | 显示全部楼层 |阅读模式
书目名称Silicon Containing Copolymers
编辑Sahar Amiri,Mohammad Ali Semsarzadeh,Sanam Amiri
视频video
概述New polyrotaxane based on PDMS.New method for synthesis of new block copolymers.New application for PDMS based copolymers as thermoreversible block copolymers.Includes supplementary material:
丛书名称SpringerBriefs in Molecular Science
图书封面Titlebook: Silicon Containing Copolymers;  Sahar Amiri,Mohammad Ali Semsarzadeh,Sanam Amiri Book 2014 The Author(s) 2014 Block Copolymers.Cobalt Media
描述Silicones have unique properties including thermal oxidative stability, low temperature flow, high compressibility, low surface tension, hydrophobicity and electric properties. These special properties have encouraged the exploration of alternative synthetic routes of well defined controlled microstructures of silicone copolymers, the subject of this Springer Brief. The authors explore the synthesis and characterization of notable block copolymers. Recent advances in controlled radical polymerization techniques leading to the facile synthesis of well-defined silicon based thermo reversible block copolymers are described along with atom transfer radical polymerization (ATRP), a technique utilized to develop well-defined functional thermo reversible block copolymers. The brief also focuses on Polyrotaxanes and their great potential as stimulus-responsive materials which produce poly (dimethyl siloxane) (PDMS) based thermo reversible block copolymers.
出版日期Book 2014
关键词Block Copolymers; Cobalt Mediated Radical Polymerization; Cyclodextrins Copolymers; Poly(dimethyl silox
版次1
doihttps://doi.org/10.1007/978-3-319-09225-6
isbn_softcover978-3-319-09224-9
isbn_ebook978-3-319-09225-6Series ISSN 2191-5407 Series E-ISSN 2191-5415
issn_series 2191-5407
copyrightThe Author(s) 2014
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Introduction,nd low fire hazard. Well-defined silicon-based block copolymers were synthesized via ATRP of St, MMA, MA, BDMP or VAc monomers at 60 °C using CuCl/PMDETA as a catalyst system initiated from Br-PDMS-Br. Also new polyrotaxanes were synthesized based on new copolymers via inclusion complex of γ-cyclodextrin and block copolymers.
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,Polyrotaxane Based on Inclusion Complexes of OH-PDMS-OH and Br-PDMS-Br with γ-Cyclodextrin Without characterized by XRD, DSC, .H-NMR and FT-IR spectroscopy. The findings suggest that the reaction conditions change the crystalline structure and mole ratios of the complexes (monomer unit/γ-CD) determined by .H-NMR spectroscopy for all of the ICs with γ-CD.
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Introduction,e block copolymers. Because of their inorganic–organic structure and the flexibility of the silicone bonds, silicones have some unique properties including thermal oxidative stability, low temperature flow ability, high compressibility, low surface tension, hydrophobicity, good electric properties a
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Synthesis and Characterization of PDMS Based Triblock and Pentablock Copolymers,and vinyl acetate (VAc) telomer at 60 °C in the presence of CuCl/PMDETA as a catalyst system initiated with bis(bromoalkyl)- terminated PDMS macroinitiator (Br-PDMS-Br). Vinyl acetate telomers prepared from radical and controlled radical telomerization with Co(acac)./DMF catalyst and ligand were use
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Cobalt Mediated Radical Polymerization of 4-Bromo-2,6-Dimethyl Phenol and Its Copolymerization withalt acetylacetonate (Co(acac).) catalyst with dimethyl formamide (DMF) as a ligand and initiated with benzoyl peroxide (BPO) at 60 °C in a novel controlled copolymerization reaction within a good yield. The monomer copolymerized with vinyl acetate (VAc), poly(methyl methacrylate)-b-poly(dimethyl sil
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Synthesis and Characterization of PDMS Based Triblock and Pentablock Copolymers,lock copolymer on a well-defined microstructure. The results were confirmed by .H-NMR and DSC indicating that a low Tg of PDMS in the microstructure of block copolymer has made the block copolymer flexible for new applications.
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