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Titlebook: Silicon Chemistry; Ulrich Schubert Conference proceedings 1999 Springer-Verlag Wien 1999 Compound.Polymerwissenschaften.Silicon.Silikon.po

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Conference proceedings 1999isticated special materials, from ceramics to polymers, from medicine to microelectronics. To keep pace with scientific and technical developments Germany and Austria have established national priority programs, strongly linked to each other as well as to some Swiss groups.At mid-term of the German
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,A Zwitterionic λ,,-Silicate with an Almost Ideal Square-Pyramidal Si Coordination Polyhedron: Synththe basal positions being occupied by the four oxygen atoms of the two diolato(2−) ligands. Significant differences between the isotropic .Si chemical shifts of 4.CH.CN in the crystal (δ=−85.1) and in solution (δ=−131.9, ..) indicate special structural features in solution.
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,Gezielte Synthese siloxenähnlicher Polymerer,or products derived from linear silane units. The fluorescence is influenced by the functionality of the siloxane networks as shown in a comparison of cyclosilane compounds with one functionality per ring up to species with two functionalities per each silicon atom of the ring.
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Preparation and Characterization of Epitaxial CaSi2 and Siloxene Layers on Silicon,opy as well as X-ray diffraction analysis. Siloxene on (110)-Si enables direct observation of the anisotropic vibrational properties by IR transmission measurements. A diode structure was realized with siloxene by using contacts with different work functions as charge carrier injectors.
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Preparation and Structure of 1-(Trifluoromethyl)silatrane,quatorial Si-0 bond lengths of the almost perfect trigonal bipyramid average 165.3(2) pm, the axial Si-C bond length is 94.6(1) pm. The transannular Si-N contact, 202.4(1) pm, is considerably shorter than in other organylsilatranes.
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