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Titlebook: Rotational Dynamics of Small and Macromolecules; Proceedings of a Wor Th. Dorfmüller,R. Pecora Conference proceedings 1987 Springer-Verlag

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书目名称Rotational Dynamics of Small and Macromolecules
副标题Proceedings of a Wor
编辑Th. Dorfmüller,R. Pecora
视频video
丛书名称Lecture Notes in Physics
图书封面Titlebook: Rotational Dynamics of Small and Macromolecules; Proceedings of a Wor Th. Dorfmüller,R. Pecora Conference proceedings 1987 Springer-Verlag
描述The contributors to this volume study macroscopic flow properties and molecular mobility in complex liquids with high internal mobility and a highly anisotropic molecular shape. Particular attention is paid to the wide variety of experimental approaches, in theory as well as in computer simulation of these difficult but very important problems. The contributions are of interest to researchers in physics as well as in engineering and chemistry.
出版日期Conference proceedings 1987
关键词chemistry; computer simulation; dynamics; experiment; flow properties; macromolecule; macromolecules; molec
版次1
doihttps://doi.org/10.1007/BFb0032714
isbn_softcover978-3-662-13612-6
isbn_ebook978-3-540-48079-2Series ISSN 0075-8450 Series E-ISSN 1616-6361
issn_series 0075-8450
copyrightSpringer-Verlag Berlin Heidelberg 1987
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The problem of internal motion of molecules in the liquid as seen from NMR relaxation studies,ry which gives the framework of the facts to be treated. A number of experimental results are presented for the following molecules: Methanol, acetic acid, DMSO, ethanol, i-propanol, toluene and propylene carbonate. It will be shown that the proton-proton distances in the molecule which result from
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A comparative study of molecular rotation as studied by dynamic light scattering, fluorescence anissubstituted small molecules. The differences obtained by the three techniques are shown to result from the different components of the diffusion tensor observed by these methods. The simultaneous application of these techniques may allow us to better assess the rotational correlation times about all
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Molecular order and dynamics of liquid crystal polymers studied by multipulse dynamic NMR techniqueuence, pulse separation and magnetic field orientation provides the large number of independent experiments necessary for a proper molecular characterization of the systems. Analysis of these experiments in terms of molecular order and dynamics is conveniently achieved by employing a density matrix
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The elastic trumbbell model for dynamics of stiff chains,one (λ.) to bending, dominate the relaxation spectrum of viscoelasticity and Kerr Effect. As the stiffness of the spring increases, the slowest relaxation mode Ψ. becomes dominant in the Kerr Effect case (K. ≫ K.), and the decay curves fit nearly single exponentials if Z ≥ 0.75. This, however, does
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Rotation of large molecular ions and transient dielectric relaxation effects, the slip limit are useful estimates of the rotation rate for large, symmetrically charged molecules, if there are no strong solvent interactions. For cases of strong interactions, the rotation rate reduces by a factor of 5–6. For the symmetric, anionic dye molecule resorufin, we successfully modele
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