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Titlebook: Organometallic Oxidation Catalysis; Franc Meyer,Christian Limberg Book 2007 Springer-Verlag Berlin Heidelberg 2007 Organometallic chemistr

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书目名称Organometallic Oxidation Catalysis
编辑Franc Meyer,Christian Limberg
视频video
概述Each volume of "Topics in Organometallic Chemistry" provides the broad scientific readership with a comprehensive summary and critical overview of a specific topic in organometallic chemistry.Research
丛书名称Topics in Organometallic Chemistry
图书封面Titlebook: Organometallic Oxidation Catalysis;  Franc Meyer,Christian Limberg Book 2007 Springer-Verlag Berlin Heidelberg 2007 Organometallic chemistr
描述.Eighty per cent of all compounds produced in the chemical and pharmaceutical industries require at least one essential catalytic step during their synthesis. At the same time the use of hydrocarbons as a feed-stock for commodity and fine chemicals typically requires an oxidation step, which is usually mediated by a transition metal compound. Consequently oxidation catalysis is a major research field in chemistry, both in academia and in industry. In many such processes, species with metal-carbon bonds are formed as key intermediates, and these processes represent the primary focus of this volume. An important aspect covered by some of the expert contributors is the use of organic ligands - and thus organometallic complex metal fragments - to achieve efficient oxidation catalysis. It has not been self-evident that organometallic complexes can survive the conditions necessary for polar oxygen-transfer reactions, but research over the last decade concerning oxo and peroxo complexes functionalized by organic ligands has clearly shown that relatively non-polar M-C bonds can be quite stable in the presence of oxidants and protic media, and that they may even be essential for the favoura
出版日期Book 2007
关键词Organometallic chemistry; Oxidation; Synthesis; catalysis; chemistry; metals
版次1
doihttps://doi.org/10.1007/11603818
isbn_softcover978-3-642-07206-2
isbn_ebook978-3-540-37210-3Series ISSN 1436-6002 Series E-ISSN 1616-8534
issn_series 1436-6002
copyrightSpringer-Verlag Berlin Heidelberg 2007
The information of publication is updating

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Dioxygen Activation by Organometallics of Early Transition Metals,r these metals. However, the investigations ofindividual reaction steps contribute to the fundamental knowledge of organometallic chemistry, and theyare valuable for the design of catalytic oxidations.
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1436-6002 iew of a specific topic in organometallic chemistry.Research.Eighty per cent of all compounds produced in the chemical and pharmaceutical industries require at least one essential catalytic step during their synthesis. At the same time the use of hydrocarbons as a feed-stock for commodity and fine c
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Palladium-Catalyzed Oxidation Reactions: Comparison of Benzoquinone and Molecular Oxygen as Stoichir catalyst reoxidation mechanisms. The chemical similarities between benzoquinoneand dioxygen are reinforced by catalytic reactions that undergo successful catalytic turnover with eitheror both of these oxidants. The results highlight substantial opportunities for the development of new aerobicoxidation reactions.
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