书目名称 | Organometallic Oxidation Catalysis |
编辑 | Franc Meyer,Christian Limberg |
视频video | |
概述 | Each volume of "Topics in Organometallic Chemistry" provides the broad scientific readership with a comprehensive summary and critical overview of a specific topic in organometallic chemistry.Research |
丛书名称 | Topics in Organometallic Chemistry |
图书封面 |  |
描述 | .Eighty per cent of all compounds produced in the chemical and pharmaceutical industries require at least one essential catalytic step during their synthesis. At the same time the use of hydrocarbons as a feed-stock for commodity and fine chemicals typically requires an oxidation step, which is usually mediated by a transition metal compound. Consequently oxidation catalysis is a major research field in chemistry, both in academia and in industry. In many such processes, species with metal-carbon bonds are formed as key intermediates, and these processes represent the primary focus of this volume. An important aspect covered by some of the expert contributors is the use of organic ligands - and thus organometallic complex metal fragments - to achieve efficient oxidation catalysis. It has not been self-evident that organometallic complexes can survive the conditions necessary for polar oxygen-transfer reactions, but research over the last decade concerning oxo and peroxo complexes functionalized by organic ligands has clearly shown that relatively non-polar M-C bonds can be quite stable in the presence of oxidants and protic media, and that they may even be essential for the favoura |
出版日期 | Book 2007 |
关键词 | Organometallic chemistry; Oxidation; Synthesis; catalysis; chemistry; metals |
版次 | 1 |
doi | https://doi.org/10.1007/11603818 |
isbn_softcover | 978-3-642-07206-2 |
isbn_ebook | 978-3-540-37210-3Series ISSN 1436-6002 Series E-ISSN 1616-8534 |
issn_series | 1436-6002 |
copyright | Springer-Verlag Berlin Heidelberg 2007 |