Titlebook: Optical Activity and Chiral Discrimination; Stephen F. Mason Book 1979 Springer Science+Business Media B.V. 1979 Enantiomer.Isomer.chemist

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The Optical Activity of Lanthanide and Transition Metal Complexesyears. The optical rotatory properties of coordination compounds have played a prominent and venerable role in the development of inorganic stereochemical analysis and structure elucidation, and experimental and theoretical research in this area has been particularly intense over the past 20 years.

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The Ligand Polarization Model for the Spectra of Metal Complexestatic-field model virtually monopolised the independent-systems approach to the problem over the two decades following the pioneer work of Moffitt [1] in 1956. In contrast, the dynamic-coupling and the staticfield methods received comparable attention in discussions of chiral organic compounds over

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Raman Optical Activityg in right and left circularly polarized incident light. This technique enables complete vibrational optical activity spectra from about 50 to 4000 cm. to be measured routinely, although the largest effects occur at low frequency. The basic theory of Raman optical activity is developed, together wit

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因无茶而冷淡

Filibuster

Chiral Discriminationles or ions is different for the two enantiomers of one acting on the same enantiomer of the other there is chiral discrimination. In its application to small molecules, at distances greater than closest approach, where the molecules had some freedom of rotation, the current revival of interest stem

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The Dispersion and other Chiral Discriminationsammonium salts of tartaric and racemic acid, Graham continued, ‘not only coincide in the proportion of their water and other constituents, and in the composition of their acids, but also in their external form, having been observed by Mitscherlich to be isomorphous’ [1]. Aware of Herschel’s correlat

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978-90-481-8355-5Springer Science+Business Media B.V. 1979

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