书目名称 | Model Systems in Catalysis | 副标题 | Single Crystals to S | 编辑 | Robert Rioux | 视频video | | 概述 | Synthesis of all three branches of catalysis (heterogeneous, homogeneous, enzymatic).Extensive listing of distinguished scientists in the field of catalysis as chapter authors.Includes supplementary m | 图书封面 |  | 描述 | This book is an excellent compilation of cutting-edge research in heterogeneous catalysis and related disciplines – surface science, organometallic catalysis, and enzymatic catalysis. In 23 chapters by noted experts, the volume demonstrates varied approaches using model systems and their successes in understanding aspects of heterogeneous catalysis, both metal- and metal oxide-based catalysis in extended single crystal and nanostructured catalytic materials. To truly appreciate the astounding advances of modern heterogeneous catalysis, let us first consider the subject from a historical perspective. Heterogeneous catalysis had its beginnings in England and France with the work of scientists such as Humphrey Davy (1778–1829), Michael Faraday (1791–1867), and Paul Sabatier (1854–1941). Sabatier postulated that surface compounds, si- lar to those familiar in bulk to chemists, were the intermediate species leading to catalytic products. Sabatier proposed, for example, that NiH moieties on a Ni sur- 2 face were able to hydrogenate ethylene, whereas NiH was not. In the USA, Irving Langmuir concluded just the opposite, namely, that chemisorbed surface species are chemically bound to surfa | 出版日期 | Book 2010 | 关键词 | Cluster; Model Systems; Rioux; catalysis; enzyme mimics; heterogeneous catalysis; homogeneous catalysis; si | 版次 | 1 | doi | https://doi.org/10.1007/978-0-387-98049-2 | isbn_softcover | 978-1-4614-9739-4 | isbn_ebook | 978-0-387-98049-2 | copyright | Springer-Verlag New York 2010 |
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