| 书目名称 | MWW-Type Titanosilicate |
| 副标题 | Synthesis, Structura |
| 编辑 | Peng Wu,Hao Xu,Mingyuan He |
| 视频video | |
| 概述 | Provides a complete overview of the Ti-MWW catalyst.Describes detailed synthesis methods for preparing Ti-MWW that differ from conventional techniques.Shows the special role of Ti-MWW titanosilicate i |
| 丛书名称 | SpringerBriefs in Molecular Science |
| 图书封面 |  |
| 描述 | .This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.. |
| 出版日期 | Book 2013 |
| 关键词 | Aldehyde Ammoximation; Alkene Epoxidation; Heterogeneous Catalysis; Hydrogen Peroxide; Ketone Ammoximati |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-642-39115-6 |
| isbn_softcover | 978-3-642-39114-9 |
| isbn_ebook | 978-3-642-39115-6Series ISSN 2191-5407 Series E-ISSN 2191-5415 |
| issn_series | 2191-5407 |
| copyright | The Author(s) 2013 |
发表于 2025-3-21 19:29:38
