书目名称 | Iron-Catalyzed Synthesis of Fused Aromatic Compounds via C–H Bond Activation |
编辑 | Arimasa Matsumoto |
视频video | http://file.papertrans.cn/476/475418/475418.mp4 |
概述 | Nominated by The University of Tokyo as an outstanding Ph.D. thesis.Provides examples of C-H bond activation which has attracted attention as an important chemical reaction in organic chemistry.Shows |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon–hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C–H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society. |
出版日期 | Book 2014 |
关键词 | Alkyne Annulation; C–H Bond Activation; Fused Aromatic Compounds; Iron Catalysis; Iron Catalyst; Naphthal |
版次 | 1 |
doi | https://doi.org/10.1007/978-4-431-54928-4 |
isbn_softcover | 978-4-431-56248-1 |
isbn_ebook | 978-4-431-54928-4Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer Japan 2014 |