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Titlebook: Hydrophobic Interactions; Arieh Ben-Naim Book 1980 Plenum Press, New York 1980 NMR.biological.electrolyte.enthalpy.entropy.experiment.kine

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发表于 2025-3-21 19:19:04 | 显示全部楼层 |阅读模式
书目名称Hydrophobic Interactions
编辑Arieh Ben-Naim
视频video
图书封面Titlebook: Hydrophobic Interactions;  Arieh Ben-Naim Book 1980 Plenum Press, New York 1980 NMR.biological.electrolyte.enthalpy.entropy.experiment.kine
描述My personal involvement with the problem of hydrophobic interactions (HI) began about ten years ago. At that time I was asked to write a review article on the properties of aqueous solutions of nonpolar solutes. While surveying the literature on this subject I found numerous discussions of the concept of HI. My interest in these interactions increased especially after reading the now classical review of W. Kauzmann (1959), in which the importance of the HI to biochemical processes is stressed. Yet, in spite of having read quite extensively on the various aspects of the subject, I acquired only a very vague idea of what people actually had in mind when referring to HI. In fact, it became quite clear that the term HI was applied by different authors to describe and interpret quite different phenomena occurring in aqueous solutions. Thus, even the most fundamental question of the very definition of the concept of HI remained unanswered. But other questions followed, e. g. : Are HI really a well­ established experimental fact? Is there any relation between HI and the peculiar properties of water? Is the phenomenon really unique to aqueous solutions? Finally, perhaps the most crucial qu
出版日期Book 1980
关键词NMR; biological; electrolyte; enthalpy; entropy; experiment; kinetics; phenol; structure; thermodynamics; wate
版次1
doihttps://doi.org/10.1007/978-1-4684-3545-0
isbn_softcover978-1-4684-3547-4
isbn_ebook978-1-4684-3545-0
copyrightPlenum Press, New York 1980
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发表于 2025-3-21 22:05:04 | 显示全部楼层
Very Dilute Solutions and Hydrophobic Interaction,ver, they are quite different, and in general one cannot infer anything about one quantity from the other. In fact we shall see in Section 3.4 that in some cases they provide an apparently contradictory result as to the degree of “phobia” for two solvents.
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Pairwise Hydrophobic Interaction (HI), broad sense. In fact, there always exists some ambiguity in the very definition of a dimer formed by two solute particles. Although we shall be discussing dimers formed by complex solute molecules, we shall restrict ourselves first to simple spherical solute molecules.
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Arieh Ben-Naim Umkehrung nicht gilt. So gibt es eine Existenz von Nucleinsäuren ohne eigenständiges Leben bei den Viren. Lebensfunktionen sind stets an Organismen gebunden und es existieren mehr als 30 Mio. Tier- und Pflanzenarten auf der Erde. Deren außerordentliche Mannigfaltigkeit ist das Ergebnis einer differ
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发表于 2025-3-23 03:57:45 | 显示全部楼层
Arieh Ben-Naim Umkehrung nicht gilt. So gibt es eine Existenz von Nucleinsäuren ohne eigenständiges Leben bei den Viren. Lebensfunktionen sind stets an Organismen gebunden und es existieren mehr als 30 Mio. Tier- und Pflanzenarten auf der Erde. Deren außerordentliche Mannigfaltigkeit ist das Ergebnis einer differ
发表于 2025-3-23 07:57:57 | 显示全部楼层
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