书目名称 | Free Radicals in Synthesis and Biology | 编辑 | Francesco Minisci | 视频video | | 丛书名称 | Nato Science Series C: | 图书封面 |  | 描述 | Free-radical reactions have been for long time the domain of the physical chemists and the basic chemical industry (polymerization of vinyl monomers, oxidation by molecular oxygen, chlorination of methane etc.), where the use of simple molecules and the possibility of partial conversions without heavy problems of product separations makes less dramatic the aspects of regio and chemoselectivity. As synonym of unselectivity, free radical reactions were considered of poor use in the synthesis of fine chemicals or sophisticated molecules, where a high selectivity is an essential condition for the success, or in the involvement of biological processes. Within the last 15 years, however, an authentic explosion of synthetic applications of free radical reactions occurred; they have gained a remarkable position among the selective methods of synthesis. At the same time the great importance of free radical reactions in fundamental biological processes and in the metabolism of drugs has been recognized. Thus a specialized meeting on these topics was generally felt appropriate. I had the honour and the onus to organize this workshop because for more than 30 years I have been involved in the r | 出版日期 | Book 1989 | 关键词 | Base; DNA; Nucleotide; Oxidation; Rearrangement; biochemistry; metabolism | 版次 | 1 | doi | https://doi.org/10.1007/978-94-009-0897-0 | isbn_softcover | 978-94-010-6892-5 | isbn_ebook | 978-94-009-0897-0Series ISSN 1389-2185 | issn_series | 1389-2185 | copyright | Kluwer Academic Publishers 1989 |
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