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Titlebook: Elements of Organic Photochemistry; Dwaine O. Cowan,Ronald L. Drisko Book 1976 Plenum Press, New York 1976 Aldehyde.Alkene.Cycloaddition.K

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书目名称Elements of Organic Photochemistry
编辑Dwaine O. Cowan,Ronald L. Drisko
视频video
图书封面Titlebook: Elements of Organic Photochemistry;  Dwaine O. Cowan,Ronald L. Drisko Book 1976 Plenum Press, New York 1976 Aldehyde.Alkene.Cycloaddition.K
描述In the past fifteen years organic photochemistry has undergone a greater change and has stimulated more interest than probably any other area of organic chemistry. What has resulted is a population explosion, that is, an ever-increasing number of organic chemists are publishing important and exciting research papers in this area. Professor Bryce-Smith in the introduc­ tion to a recent volume of the Specialist Periodical Report (Photochemistry, Volume 6), which reviews the photochemical literature in yearly intervals, states that "the flood of photochemical literature is showing some signs of abatement from the high levels of two or three years ago .... " However, Volume 6 of that periodical contains 764 pages of excellent but very concise reviews. We expect the development of the mechanistic aspects of organic photo­ chemistry to continue at the present pace as new methods are developed to probe in increasing detail and shorter time scales the photochemical dynamics of both old and new photoreactions. Since photochemistry is no longer the sole domain of the specialist, it is relatively safe to predict a dramatic increase in the near future of the synthetic and industrial uses of or
出版日期Book 1976
关键词Aldehyde; Alkene; Cycloaddition; Ketone; aromatic; carbon; cyclic compound; heterocyclic compound; organic c
版次1
doihttps://doi.org/10.1007/978-1-4684-2130-9
isbn_softcover978-1-4684-2132-3
isbn_ebook978-1-4684-2130-9
copyrightPlenum Press, New York 1976
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The Triplet State,state than the singlet? How are its properties different from the singlet? How are these properties determined? In this chapter we will attempt to answer these and other questions concerning the nature of the triplet state.
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Basic Photophysical and Photochemical Concepts,rth’s reducing atmosphere (methane, ammonia, and hydrogen). However, from man’s point of view, the greatest photochemical “breakthrough” occurred when the first few quanta of light were absorbed by a rudimentary photosynthetic unit, resulting in the release of molecular oxygen to the atmosphere, thus paving the way for all higher life:
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https://doi.org/10.1007/978-3-540-85186-8self rearranges into a linearly conjugated dienone (3). The dienone (3) can be isolated from the photolysis of either (1) or (2) in benzene or ether. In nucleophilic solvents (alcohol or water) the dienone (3) is also photo-chemically active and is further converted into an ester or an acid (photo-santonic acid) (4).
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https://doi.org/10.1007/978-3-322-87398-9s, but since the excellent physical tools commonly available to the present-day photochemist were lacking, the stereochemistry of the products often remained completely obscure. A review of the reactions discovered and investigated prior to the rapid acceleration in photochemical progress of the past twenty years is given by Mustafa..
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