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Titlebook: Elementary Reaction Steps in Heterogeneous Catalysis; R. W. Joyner,R. A. Santen Book 1993 Springer Science+Business Media Dordrecht 1993 I

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Literature and the Peripheral Citysical science. Progress is encouraged by parallel developments in surface science, in . methods suitable for studies of the working catalyst, in our understanding of reactivity, kinetics and mechanism, and of relevant and cognate theoretical studies. This improved insight into catalysis at the molec
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https://doi.org/10.1007/978-1-349-27297-6ehavior. These include trends of reactivity and bonding across the periodic table; the observation that rough surfaces and defect sites have high reaction rates and more strongly bind the adsorbates; the reaction and chemisorption induced restructuring of metal surfaces; and the presence of a strong
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https://doi.org/10.1057/9781137287427l product distribution is known, while the nature of the catalyst-reactant interactions remains obscure. In a few cases, more detailed mechanistic proposals have been advanced, but they remain modest in scope compared to the detailed mechanisms that have been developed in molecular organic chemistry
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https://doi.org/10.1007/978-1-349-19286-1ast half century. A convincing case is provided that the site densities are low and very often mononuclear rather than ensembles of two or more contiguous atoms. The mechanisms of reaction are then due to the interconversion of various transient intermediates as ligands of these mononuclear centres,
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Vivid Girmitiya Sacraments and Ganga TalaoY.O.-doped-ZrO., an O. conductor, or β“-Al.O., a Na. conductor, and by supplying or removing ions to or from the metal catalyst surface via application of an external voltage. The induced change in catalytic rate can be up to 3 ×0. times higher than the rate of ion supply and up to 70 times higher t
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Literature of Mysticism in Western Traditioned in relation to the results reported in the literature on the nature of active sites and mechanisms of reaction in alkene selective oxidation, in order to evidence which new aspects about the elementary steps, selective oxidation pathways and surface characteristics of oxide catalysts derive from
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Literature of an Independent Englandce on zeolite structure as well as composition. The zeolitic OH bond is mainly covalent. Proton attachment to the zeolite lattice causes a weakening of neighbouring Si-O and Al-O bonds. The effective increase in volume of the bridging oxygen atom causes a local deformation, that changes the strength
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Conclusion: Degrees of Freedom,sed. Among them the surface crystal field displayed by a catalyst, depending on its structure and on crystal morphology, is shown to be the primary factor. With the help of knowledge on methane coupling and butane oxidation, sites needed to activate and oxygenate molecules are proposed for alkanes.
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https://doi.org/10.1057/9781137318015the differences in behaviour of the Group VIII metal surfaces in reactions of oxygen with hydrogen and carbon monoxide; nitric oxide with hydrogen and carbon monoxide; carbon monoxide with hydrogen; and ammonia with nitric oxide and oxygen. It will be shown that the differences in activity and selec
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