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Titlebook: Electron Deficient Compounds; K. Wade Book 1971 K. Wade 1971 Diboran.aluminium.boron.lithium.metals

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发表于 2025-3-21 17:34:59 | 显示全部楼层 |阅读模式
书目名称Electron Deficient Compounds
编辑K. Wade
视频video
丛书名称Studies in Modern Chemistry
图书封面Titlebook: Electron Deficient Compounds;  K. Wade Book 1971 K. Wade 1971 Diboran.aluminium.boron.lithium.metals
描述This book is about compounds such as the boron hydrides and associated metal hydrides and alkyls which acquired the label ‘electron deficient‘ when they were thought to contain too few valence electrons to hold together. Though they are now recognized as containing the numbers of bonding electrons appropriate for their structures, the term ‘electron deficient‘ is still commonly applied to many substances that contain too few valence electrons to provide a pair for every pair of atoms close enough to be regarded as covalently bonded. The study of such substances has contributed much to chemistry. Techniques for the vacuum manipulation of volatile substances were devised specifically for their study; developments in valence theory resulted from considerations of their bonding; and the reactivity of several (for example, diborane and complex metal hydrides, lithium and aluminium alkyls) has made them valuable reagents. The purpose of this book is to provide an introduction to the chemistry of these fascinating compounds. The experimental and spectroscopic methods by which they can be studied are outlined, the various types of structure they adopt are described and profusely illustrate
出版日期Book 1971
关键词Diboran; aluminium; boron; lithium; metals
版次1
doihttps://doi.org/10.1007/978-1-4684-6054-4
isbn_softcover978-1-4684-6056-8
isbn_ebook978-1-4684-6054-4
copyrightK. Wade 1971
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Higher Education in the Arab WorldThis book is about compounds with too few valence electrons to provide a pair for every pair of atoms close enough to be regarded as covalently bonded.
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Introduction,This book is about compounds with too few valence electrons to provide a pair for every pair of atoms close enough to be regarded as covalently bonded.
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Yew Meng Lai,Abdul Razak Ahmad,Chang Da Wannd feeble intermolecular forces. Their reactivities have a thermodynamic origin in that these compounds are markedly unstable with respect to replacement of their boron-boron and boron-hydrogen links by bonds to more electronegative elements. Some thermodynamic data bearing on this are in Tables 4-1
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,Narratives of Class and ‘Race’,be allocated to every pair of atoms close enough to be regarded as covalently bonded. The types of compound covered by this definition have included at one extreme substances like diborane, in which the electron deficiency is effectively localized in one section of the molecule, a section which acco
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