Titlebook: Electrified Interfaces in Physics, Chemistry and Biology; R. Guidelli Book 1992 Springer Science+Business Media Dordrecht 1992 biology.che

exorbitant

Single Crystal Electrodes,ieved only if the structure and composition of the interphase is well-defined. Techniques for the production of such interphases will be described as well as methods for verifying that a satisfactory interphase has been achieved. Examples of the information about interfacial structure which may be d

Cumulus

Modeling of Metal-Water Electrified Interfaces,he potential difference across the interface, the differential capacity and the entropy of formation of the interface, after correcting these thermodynamic quantities for the diffuse layer on the basis of the Gouy-Chapman theory. The contribution to the entropy of formation of the interface from the

Analogy

Molecular Models of Organic Adsorption from Water at Charged Interfaces,xperimental electrosorption behaviour of simple aliphatic compounds on sp metals. The fundamental role played by H-bonding between interfacial water molecules in determining the main distinguishing features of organic adsorption at electrodes is stressed. Since the energy of H-bonds is almost one or

DAUNT

forebear

CURT

LEER

The Solid-Electrolyte Interface as Exemplified by Hydrous Oxides; Surface Chemistry and Surface Reaonstants can be corrected for electrostatic effects by considering the Gouy Chapman theory. The surface reactivity depends on surface structure (surface speciation). A general rate law on the surface controlled dissolution of oxide minerals can be derived by combining concepts of surface coordinatio

TSH582

Ab-Initio Molecular Dynamics: Selected Applications to Disordered Systems and Surfaces,erials which had been inaccessible until a few years ago. Selected applications of the Car-Parrinello method to liquids and surfaces are presented. In particular, some properties of liquid carbon, the high-pressure region of the carbon phase diagram and some properties of the (111) surface of silicon are discussed in detail.

antecedence

遵循的规范

Stark Effect on Adsorbates at Electrified Interfaces,specific behaviour of SiH and SiOH vibrational bands in the Si-SiO. system and of H.O., H.O, D.O bands of the Si-electrolyte interface will be discussed. The dependence of these bands upon the electric field will be studied and a few conclusions will be drawn.