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Titlebook: Crown Ethers and Phase Transfer Catalysis in Polymer Science; Lon J. Mathias,Charles E. Carraher Book 1984 Plenum Press, New York 1984 cat

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书目名称Crown Ethers and Phase Transfer Catalysis in Polymer Science
编辑Lon J. Mathias,Charles E. Carraher
视频videohttp://file.papertrans.cn/241/240464/240464.mp4
丛书名称Polymer Science and Technology Series
图书封面Titlebook: Crown Ethers and Phase Transfer Catalysis in Polymer Science;  Lon J. Mathias,Charles E. Carraher Book 1984 Plenum Press, New York 1984 cat
描述Phase transfer catalysis or interfacial catalysis is a syn­ thetic technique involving transport of an organic or inorganic salt from a solid or aqueous phase into an organic liquid where reaction with an organic-soluble substrate takes place. Over the past 15 years there has been an enormous amount of effort invested in the development of this technique in organic synthe­ sis. Several books and numerous review articles have appeared summarizing applications in which low molecular weight catalysts are employed. These generally include either crown ethers or onium salts of various kinds. While the term phase transfer catalysis is relatively new, the concept of using a phasetrans­ fer agent (PTA) is much older~ Both Schnell and Morgan employed such catalysts in synthesis of polymeric species in the early 1950‘s. Present developments are really extensions of these early applications. It has only been within the last several years that the use of phase transfer processes have been employed in polymer synthesis and modification. Similarly, the use of polymer-bound phase transfer agents is also a recent development. These and related areas have nonetheless enjoyed explosive growth as mea
出版日期Book 1984
关键词catalysis; polymer science; polymer synthesis
版次1
doihttps://doi.org/10.1007/978-1-4615-9349-2
isbn_softcover978-1-4615-9351-5
isbn_ebook978-1-4615-9349-2Series ISSN 0093-6286
issn_series 0093-6286
copyrightPlenum Press, New York 1984
The information of publication is updating

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Chemical Modification of Chloromethylated Polystyrene with Phosphine Oxides Using Phase-Transfer Catlogy .. Chemical modification is an important procedure for the preparation of polymeric reagents. Phase transfer catalysis which has been widely used in organic chemistry, has found an increasing number of applications in the chemical modification of polymers having reactive functional groups, over
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Influence of Quaternary Ammonium Salts on Cellulose Modificationand b) development of techniques to control distribution of substituents along the cellulose backbone. Homogeneous substitution,i.e., random distribution of substituents among all the anhydroglucose units in the chain,can be accomplished by initial dissolution of the cellulose substrate followed by
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Effect of Triethylamine on the Synthesis of Group IV B Polyethersix on polyesters, . Morgan on polyurethanes and polyamides . and Carraher on metal-containing polymers and phosphorus-containing products. . The method has many variations and is a highly effective procedure for the rapid synthesis of many products. Until recently the technique emphasized the synthe
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Phase Transfer Free Radical Reactions:1 Polymerization of Acrylic Monomersques of PTC have been concerned for the most part with the transfer of anionic reagents between two immiscible phases for subsequent nucleophilic reactions, the concept is believed to be much more general.. Recently, for instance, a few examples describing extension of the process to cationic (elect
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Anionic Polymerizations with Complex Bases and Their Derivatives or modulate the reactivity of these classical initiators, the influence of additives (such as tertiary amines, linear and macrocyclic polyethers, cryptands, alcohols and alkoxides) has been the subject of many works..
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