书目名称 | Construction and Reactivity of Pt-Based Bi-component Catalytic Systems |
编辑 | Rentao Mu |
视频video | |
概述 | Nominated by the Chinese Academy of Sciences as an outstanding PhD thesis.Outlines the development of Pt-based bi-component catalysts.Elucidates the correlation between the surface structure and react |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | In this thesis, the author outlines the construction of active structure and modulation of catalytic reactivity of Pt-based bi-component catalysts, from the model systems to real supported catalysts. The thesis investigates the promotion effect of the second components on catalytic performance of Pt catalysts, and presents the reversible generation of the “sandwich-like” structure of Pt-Ni catalysts, containing both surface NiO1-X and subsurface Ni by alternating redox treatments at medium temperature. With the aid of single layer graphene, the dynamic process of chemical reactions occurring on the Pt(111) surface can be visualized using in-situ LEEM and DUV-PEEM techniques, the results of which are included here. The author reveals that the graphene layer exhibits a strong confinement effect on the chemistry of molecules underneath and the intercalated CO can desorb from the Pt surface around room temperature and in UHV, which may promote the CO oxidation confined under graphene. |
出版日期 | Book 2017 |
关键词 | Bi-component catalysts; Confinement effect; Nanocatalysis; Pt-Ni bimetallic catalysts; Redox treatments; |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-662-55244-5 |
isbn_softcover | 978-3-662-57226-9 |
isbn_ebook | 978-3-662-55244-5Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | Springer-Verlag GmbH Germany 2017 |