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Titlebook: Chemical Transformations of Vinylidenecyclopropanes; Lixiong Shao,Jianmei Lu,Min Shi Book 2012 The Author(s) 2012 Brønsted acid.Cycloaddit

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书目名称Chemical Transformations of Vinylidenecyclopropanes
编辑Lixiong Shao,Jianmei Lu,Min Shi
视频videohttp://file.papertrans.cn/225/224458/224458.mp4
概述Includes supplementary material:
丛书名称SpringerBriefs in Molecular Science
图书封面Titlebook: Chemical Transformations of Vinylidenecyclopropanes;  Lixiong Shao,Jianmei Lu,Min Shi Book 2012 The Author(s) 2012 Brønsted acid.Cycloaddit
描述Modern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs.
出版日期Book 2012
关键词Brønsted acid; Cycloaddition reaction; Lewis acid; Rearrangement reaction; Transition metal; Vinylidenecy
版次1
doihttps://doi.org/10.1007/978-3-642-27573-9
isbn_softcover978-3-642-27572-2
isbn_ebook978-3-642-27573-9Series ISSN 2191-5407 Series E-ISSN 2191-5415
issn_series 2191-5407
copyrightThe Author(s) 2012
The information of publication is updating

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S. Fu,Z. X. Xiao,J. B. Huang,Y. F. ZhangTransition metals such as palladium and rhodium-catalyzed transformations of vinylidenecyclopropanes are introduced in this chapter.
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Dirk Hartmann,Herman Van der AuweraerThe reactions of vinylidenecyclopropanes (VDCPs) ., which cannot be classified into the foregoing chapters, are shown in this chapter. In this chapter, Brønsted base-mediated as well as radical reaction, cycloaddition reaction and oxidation reaction of vinylidenecyclopropanes are displayed.
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Reactions of VDCPs with Electrophiles,Reactions of vinylidenecyclopropanes with a variety of electrophiles such as diaryl diselenide, iodine, bromine, .-fluorodibenzenesulfonimide (NFSI), and .-bromosuccinimide are shown in this chapter.
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Miscellaneous Analogs,The reactions of vinylidenecyclopropanes (VDCPs) ., which cannot be classified into the foregoing chapters, are shown in this chapter. In this chapter, Brønsted base-mediated as well as radical reaction, cycloaddition reaction and oxidation reaction of vinylidenecyclopropanes are displayed.
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