书目名称 | Chemical Transformations of Vinylidenecyclopropanes | 编辑 | Lixiong Shao,Jianmei Lu,Min Shi | 视频video | http://file.papertrans.cn/225/224458/224458.mp4 | 概述 | Includes supplementary material: | 丛书名称 | SpringerBriefs in Molecular Science | 图书封面 |  | 描述 | Modern organic synthesis has paid much attention to the chemistry of small carbocycles. Vinylidenecyclopropanes (VDCPs), which have strained cyclopropyl group connected with an allene moiety and yet are thermally stable and reactive substances in organic chemistry, are versatile intermediates in organic synthesis. In this volume, Dr. Lixiong Shao, Dr. Jianmei Lu and Prof. Dr. Min Shi review their investigations on the chemistry of VDCPs, mainly including the preparation, the reactivities upon treatment with Lewis or Brønsted acid, as well as transition metal catalysts and some other miscellaneous analogues. The contributions aroused a renaissance of cationic intermediates in the chemistry of VDCPs. | 出版日期 | Book 2012 | 关键词 | Brønsted acid; Cycloaddition reaction; Lewis acid; Rearrangement reaction; Transition metal; Vinylidenecy | 版次 | 1 | doi | https://doi.org/10.1007/978-3-642-27573-9 | isbn_softcover | 978-3-642-27572-2 | isbn_ebook | 978-3-642-27573-9Series ISSN 2191-5407 Series E-ISSN 2191-5415 | issn_series | 2191-5407 | copyright | The Author(s) 2012 |
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