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Titlebook: Chemical Reactivity in Liquids; Fundamental Aspects Michel Moreau,Pierre Turq Book 1988 Plenum Press, New York 1988 Adsorption.Chemical rea

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书目名称Chemical Reactivity in Liquids
副标题Fundamental Aspects
编辑Michel Moreau,Pierre Turq
视频video
图书封面Titlebook: Chemical Reactivity in Liquids; Fundamental Aspects Michel Moreau,Pierre Turq Book 1988 Plenum Press, New York 1988 Adsorption.Chemical rea
描述Understanding chemical reactivity has been the permanent concern of chemists from time immemorial. If we were able to understand it and express it quantitatively there would practically remain no unsolved mystery, and reactions would be fully predictable, with their products and rates and even side reactions. The beautiful developments of thermodynamics through the 19th century supplied us with the knowledge of the way a reactions progresses, and the statistical view initiated by Gibbs has progressively led to an unders­ tanding closer to the microscopic phenomena. But is was always evident to all that these advances still left our understanding of chemical reactivity far behind our empirical knowledge of the chemical reaction in its practically infinite variety. The advances of recent years in quantum chemistry and statistical mechanics, enhanced by the present availability of powerful and fast compu­ ters, are very fast changing this picture, and bringing us really close to a microscopic understanding of chemical equilibria, reaction rates, etc.... This is the reason why our Society encouraged a few years ago the initiative of Professor Savo Bratos who, with a group of French col
出版日期Book 1988
关键词Adsorption; Chemical reaction; Diffusion; chemistry; electrochemistry; enzymes; process engineering; spectr
版次1
doihttps://doi.org/10.1007/978-1-4613-1023-5
isbn_softcover978-1-4612-8297-6
isbn_ebook978-1-4613-1023-5
copyrightPlenum Press, New York 1988
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978-1-4612-8297-6Plenum Press, New York 1988
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Business benefits of a PLM system, as absorption, polarization and chemiluminescence spectroscopy down to the picosecond (10.s) and even femtosecond (10.s) time scale. These new techniques allow now to monitor the molecular dynamics of polar liquids and provide new results in the field of chemical or biochemical reaction dynamics: u
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Understanding the product lifecycle, instance, one may refer to proton transfer kinetic studies in strong acidic solutions., and,in a more general overview,to conformational dynamics studies about the internal rotation in methyl groups and the ring puckering motion in small cycles ..
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Principles for the PLM strategy,lutions. Information is obtained on the low and high frequency relaxation times of the solvent and their shifts by addition of electrolytes, rotational relaxation times of ion pairs, association constants, rate constants of ion-pair formation and decomposition, and kinetic depolarization. Examples a
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A Strategy to achieve the Vision,ields. Indeed it has been recently recognized that a number of so-thought elementary reactions may involve — or — may be triggered by — single electron transfers. The spreading of these new concepts coincided with the development of new experimental and conceptual tools in electrochemistry. Indeed u
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The opportunities and benefits of PLM,volution of computer hardware. The applications of N.M.R. in biology developed more slowly in line with the development of new techniques such as 2D N.M.R. This delay can be explained for technological reasons : classical supraconducting magnets were very ill adapted in particular to living systems,
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The opportunities and benefits of PLM,f experimental techniques at several temperatures, relatively little is known of their general properties in the one-phase precritical and critical regions. The coexistence curve has been previously published. The system ace-tonitrile-water has an upper critical solution temperature at 272.1K when t
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