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Titlebook: Chemical Processes in Atmospheric Oxidation; Laboratory Studies o Georges Bras Book 1997 Springer-Verlag Berlin Heidelberg 1997 EUREKA.EURO

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Scientific Resultsr OH + VOC reactions determine the timescales, and hence the spatial distribution of VOCs. The timescales of VOC loss by reaction with OH are also identical with the timescales of formation of secondary pollutants and photochemical oxidants, including ozone. The data base for OH reaction rate coeffi
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Laboratory Studies of the Atmospheric Decay of Hydrocarbons in the NOx Free Atmosphereres of aliphatic and aromatic hydrocarbons, carbonyls, alcohols and halogenated hydrocarbons. HPLC with chemiluminescence, electrochemical and fluorescence detection was used for selective detection of hydroperoxides and hydroxohydroperoxides and gas chromatography with mass spectrometric and flame
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Laboratory and Field Measurement Studies of the Tropospheric Chemistry of Nitrate and Peroxy Radicald RO. and its involvement in a potentially important night-time oxidation mechanism for VOC are discussed. Investigation of the photo-excitation of mixtures of NO., NO. and O. around 662 nm showed that reaction of NO.(A.E’) with N. is not likely to be a source of N.O and provided an upper limit for
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Scientific Resultsntical with the timescales of formation of secondary pollutants and photochemical oxidants, including ozone. The data base for OH reaction rate coefficients is generally well defined and has been the subject of regular evaluations and updates including contributions from LACTOZ. The specific objectives of LACTOZ contributions are:
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for the OH attack on more complex organic compounds, peroxy and alkoxy radical reactions, photo-oxidation of aromatic and biogenic compounds, and the interaction between radical species.978-3-642-63902-9978-3-642-59216-4
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