Titlebook: Chemical Physics of Intercalation; A. P. Legrand,S. Flandrois Book 1987 Springer Science+Business Media New York 1987 chemical physics.met

Induction

Synthesis of graphite intercalation compoundser is not a comprehensive review of GIC synthesis but a description of the thermodynamical and chemical conditions of intercalation into graphite, for a comparison with intercalation into other host lattices and, if possible, as a starting point of new syntheses. It partly develops ideas which were

发电机

尊严

Structural chemistry, phase equilibria and phase transitions in graphite intercalation compoundst together. The unifying theme is the tailoring of properties by inserting guest atoms or molecules into more-or-less well-defined interstitial sites defined by a more-or-less anisotropic host lattice. The properties of interest may be primarily electronic (e.g., synthetic metals derived from doped

显而易见

paroxysm

Comprise

Reactivity of low dimensional transition metal derivatives towards cationic intercalation chemistryelectron transfer processes. were initially developped in the case of two dimensional host structures, which actually justified utterly the name of intercalation used for these reactions. Later on, and due to the variety of fundamental topics involved and to the numerous possible applications, the i

Recess

Layered host lattices: structure, bonding, physical properties and chemical reactivity more specific characterization it is necessary to establish the geometrical structure, to describe the quality of interaction between the constituent atoms (chemical bonding) and to determine the physical properties of the compound under consideration. Presently we are at a level of knowledge that

失误

培养

Electronic structure of transition-metal chalcogenides and their intercalation compoundsen the outer orbitals of the guest atoms and the electron bands of the host during intercalation. In the transition-metal chalcogenides, the guest gives up charge to become a positive ion, and the electrons donated by the guests enter the host band structure. Thus the electronic structure of the hos

压舱物

Intercalation in oxides from 2D to 3D intercalationill the eighties, stoichiometric AMO. (A: alkali ion, M: transition element) sheet oxides have been mainly studied from a crystal chemistry point of view while only few works were devoted to A. MO. layer oxides.. During the last few years, numerous new results have been reported in this chemical fie