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Titlebook: Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers; Ayusman Sen Book 2003 Springer Science+Business Media Dordrecht

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书目名称Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers
编辑Ayusman Sen
视频videohttp://file.papertrans.cn/223/222484/222484.mp4
丛书名称Catalysis by Metal Complexes
图书封面Titlebook: Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers;  Ayusman Sen Book 2003 Springer Science+Business Media Dordrecht
描述217 2. COPOLYMERIZATION OF PROPENE OR HIGHER I-ALKENES WITH 218 CARBON MONOXIDE 2. 1. Ligands and polymerization conditions 218 2. 2. Spiroketal formation 221 2. 3. Enantioselectivity 222 2. 4. Higher I-Alkenes 226 3. COPOLYMERIZATION OF STYRENE OR ITS DERIVATIVES WITH 226 CARBON MONOXIDE 4. COPOLYMERIZATION OF OTHER OLEANS WITH CARBON MONOXIDE 230 5. ASYMMETRIC TERPOLYMERIZATION OF MORE THAN Two KINDS OF 232 OLEFINS WITH CARBON MONOXIDE 6. POLYKETONE CONFORMATION 233 7. CONCLUSION 234 Chapter 8. Chain Propagation Mechanisms 237 Ayusman Sen 1. INTRODUCTION 237 2. PALLADIUM (II) BASED SYSTEMS 238 3. NICKEL (II) BASED SYSTEMS 256 4. RHODIUM (I) BASED SYSTEMS 257 5. CONCLUSION 261 Chapter 9. Theoretical Studies on Copolymerization of Polar Monomers 265 Peter Margl, Artur Michalak, and Tom Ziegler 1. INTRODUCTION 265 2. COPOLYMERIZATION OF CARBON MONOXIDE WITH ETHYLENE 267 2. 1. Experimental and calculated rates for the insertion processes for 267 copolymerization catalysed by Pd(II) systems. 2. 2. A more detailed look at the productive and unproductive cycles 270 in copolymerization catalysed by Pd(II) complexes. 2. 2. 1. The productive cycle 270 2. 2. 2. C2H4 misinsertion into an eth
出版日期Book 2003
关键词Alkene; Ethen; Olefin; Organometallic chemistry; Propen; catalysis; chemistry; polymer
版次1
doihttps://doi.org/10.1007/978-1-4419-9266-6
isbn_softcover978-1-4613-4866-5
isbn_ebook978-1-4419-9266-6Series ISSN 0920-4652 Series E-ISSN 2215-180X
issn_series 0920-4652
copyrightSpringer Science+Business Media Dordrecht 2003
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发表于 2025-3-21 20:52:24 | 显示全部楼层
Catalytic Synthesis of Copolymers and Terpolymers,ased copolymers (Figure 4-1.) at Badische (1951) [1], a class of stable, highly active palladium-based catalysts was discovered at Shell in 1982 [2]. These catalysts are also active for the co- and terpolymerization of carbon monoxide with substituted olefins, both simple aliphatic and heteroatom fu
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Theoretical Studies on Copolymerization of Polar Monomers,l based complexes. The Reppe [1] catalyst produced only low- melting oligomers and was not used on an industrial scale. A further development of the nickel based catalyst by Klabunde [2] and Keim [3] led to the synthesis of low molecular weight copolymers.
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On Picture Making and Picture Seeinge the potential for combination into a wide range of different products. Other chapters in this book, as well as several reviews, [1–5] detail the commercial production of propanal, methyl propionate, used as a precursor to the important polymer precursor, methyl methacrylate, and perfectly alternat
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Mehmet Gulsen,Fatma Pinar Gokselased copolymers (Figure 4-1.) at Badische (1951) [1], a class of stable, highly active palladium-based catalysts was discovered at Shell in 1982 [2]. These catalysts are also active for the co- and terpolymerization of carbon monoxide with substituted olefins, both simple aliphatic and heteroatom fu
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Applying BPMS to the Public Sector Using OSS containing as a characteristic weakly coordinating anions, were introduced in 1982 [1]. The palladium chloride based catalysts studied in the sixties and seventies required high temperatures and usually led to palladium metal formation, in spite of the high carbon monoxide pressures used [2]. As we
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