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Titlebook: Activation of Unreactive Bonds and Organic Synthesis; Shinji Murai,H. Alper,A. Yamamoto Book 1999 Springer-Verlag Berlin Heidelberg 1999 A

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期刊全称Activation of Unreactive Bonds and Organic Synthesis
影响因子2023Shinji Murai,H. Alper,A. Yamamoto
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发行地址The first and only comprehensive overview of the explosive development in the field of bond activation, not only C-H but also other inert functionalities.Directed to organic and inorganic chemists.Pre
学科分类Topics in Organometallic Chemistry
图书封面Titlebook: Activation of Unreactive Bonds and Organic Synthesis;  Shinji Murai,H. Alper,A. Yamamoto Book 1999 Springer-Verlag Berlin Heidelberg 1999 A
影响因子In the last few years a large repetoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create new opportunities for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.
Pindex Book 1999
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Bruce J. Caldwell,Stephan Boehmt reports on the cleavage of allylic C-O bond that has been extensively utilized in organic synthesis the review focuses on the cleavage of single C-O bonds in esters, ethers, and anhydrides activated by transition metals. The cleavage of C-O multiple bonds is also discussed.
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https://doi.org/10.1007/978-94-011-2186-6hanistic and synthetic aspects of C-Cl activation. Oxidative addition reactions of chloroarenes to complexes of catalytic metals are discussed, along with their applications in a wide variety of reductive dechlorination, nucleophilic displacement, olefin arylation, coupling, and carbonylation reactions.
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The Austrian School in the Interwar Periodition-metal complexes through the activation of the Si-Si bonds with emphasis on the catalytic reactions of organodisilanes mediated by transition-metal complexes. The application of these catalytic reactions to organic synthesis is also mentioned briefly.
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https://doi.org/10.1057/9780230281615f abundant but traditionally unreactive molecules as synthetic precursors is becoming increasingly more attractive. A major goal of this endeavor is to devise not only better methods to produce bulk (commodity) chemicals but also to synthesize new materials for industry, medicine and research. Unrea
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Austrian Economics in Transitionus transition metal complexes. Studies have provided detailed information about the intermediates involved and the mechanism(s) of activation. Thermodynamic and kinetic selectivities have been established with several reactive metal fragments. An overview of these developments is given and new examp
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