Breach 发表于 2025-3-25 03:43:21
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Copper(I)-Catalyzed Intermolecular Borylative Exo-cyclization of Alkenyl Halides Containing Unactivimental and theoretical investigations of the reaction mechanism have also been described. This reaction provides a new method for the synthesis of alkylboronates containing strained cycloalkyl structures from simple starting materials.inflame 发表于 2025-3-25 17:47:10
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Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Aldehydes,organoboronate esters with excellent enantioselectivities. Furthermore, the products could be readily converted to the corresponding functionalized chiral alcohol derivatives through stereospecific C–C bond forming reactions involving the stereogenic C–B bond.Certainty 发表于 2025-3-26 02:09:46
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Book 2017nctionalized, complex organoboronate esters, which will find wide application in asymmetric synthesis, drug discovery, and material science. Organoboron compounds are recognized as useful reagents in organic synthesis; therefore, great effort has been devoted to the development of a simple, mild, anfatuity 发表于 2025-3-26 14:00:31
Computational Insight into the Enantioselective Borylation of Aldehydes Catalyzed by Chiral Bisphosthe presence of a proton source gave a higher reactivity and a better enantioselectivity in the borylation reaction of aldehydes with a copper(I)/(.)-DTBM-SEGPHOS complex catalyst. This study is particularly valuable toward the development and design of novel enantioselective borylation reactions with polarized carbon–heteroatom double bonds.conduct 发表于 2025-3-26 18:40:33
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