Narrative
发表于 2025-3-28 16:17:15
Determining and Understanding N-H Bond Strengths in Synthetic Nitrogen Fixation Cycles,chemistry. New approaches to this problem may offer more energy-efficient and carbon-neutral routes to this important industrial compound. Despite the ubiquity of ammine, amide, imide and diazenide ligands in coordination chemistry, little thermodynamic data is available for understanding N-H bond s
CHOKE
发表于 2025-3-28 22:45:05
Dinitrogen Fixation by Transition Metal Hydride Complexes,mplexes can incorporate dinitrogen, but they are usually difficult to induce N–N bond cleavage. In contrast, multimetallic hydride complexes can split and hydrogenate dinitrogen through cooperation of the multiple metal hydrides. In this transformation, the hydride ligands serve as the source of bot
不近人情
发表于 2025-3-29 02:17:32
,Functionalization of N2 by Mid to Late Transition Metals via N–N Bond Cleavage,ansition metal complexes. The relationships of electronic and structural parameters for the most common N.-bonding modes (end-on and side-on bridging) with N.-splitting reactivity are discussed. This analysis points towards electronic configurations with π. (end-on) and π.δ. (side-on) electrons with
参考书目
发表于 2025-3-29 04:00:48
Synthetic Nitrogen Fixation with Mononuclear Molybdenum(0) Phosphine Complexes: Occupying the ,-Posent to catalytically convert N. to ammonia. In the framework of this research area, we have prepared complexes of the type (E = N, P; P. = dppm, dmpm) in which the linear PEP ligand coordinates in a facial geometry. Similar complexes have been prepared using mixed carbene–phosphine