archetype 发表于 2025-3-30 11:05:07
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The Macromolecular Electrostatic effect in Biochemical Reactivity of the Nucleic Acids,e work of Hayes and Kollman on carboxypeptidase A , in the work of Warshel on lysozyme , in the work of Van Duijnen on the role of the a-helix dipole on the reactional properties of proteins, in particular papain etc. (For general comments see also )- The different authors difwangle 发表于 2025-3-30 21:00:27
Studies on the Mechanism of Catalysis by Thiamin: Progress and Problems,methods: (a) disappearance of the signal of (C-2)H in D.O due to H—D exchange; (b) broadening of the (C-2)H signal in H.O solution due to H—H exchange. Rates calculated from the latter method are approximately two orders of magnitude larger than those from H—D exchange.fibula 发表于 2025-3-31 01:06:32
Probing the Mechanism of Binding of the Thiamin Pyrophosphate Co-enzyme on Yeast Pyruvate Decarboxyancement in the fluorescence emission spectrum which enhancement can be subsequently quenched by the addition of thiamin pyrophosphate. The fluorescence data for the apoenzyme-Eu(III) binary complex indicate the existence of two types of binding sites with K.’s of 200 μm and (6±2) μm respectively. A无礼回复 发表于 2025-3-31 05:21:06
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A Personal History of Web Search,methods: (a) disappearance of the signal of (C-2)H in D.O due to H—D exchange; (b) broadening of the (C-2)H signal in H.O solution due to H—H exchange. Rates calculated from the latter method are approximately two orders of magnitude larger than those from H—D exchange.jumble 发表于 2025-3-31 13:23:16
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Dynamic and Statistical Aspects of Enzyme Action,and statistical aspects. From the more complete description several new proposals about enzyme action, control and evolution are advanced: some general theoretical and experimental approaches for testing these suggestions are indicated. The arguments require reference to the statistical nature of th