使无罪 发表于 2025-3-21 18:20:25
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Dynamic Relaxation Methods in Heterogeneous Catalysis,on the details of the method, one may use the terms transient method or simply dynamic approach or, in some cases, isotope jump method (or transient tracing method) when labeled species are employed .柏树 发表于 2025-3-22 04:02:39
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Dynamics of Heterogeneously Catalyzed Reactions,ence of elementary steps that accomplishes the overall reaction. For example, the mechanism of CO oxidation on Pt may be written :.Here we have assumed that CO is associatively and reversibly adsorbed and O. is dissociatively and irreversibly adsorbed at the reaction temperature. Both reactions o大方不好 发表于 2025-3-22 22:00:22
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Book 1991echniques which depend on observations under non steady state conditions (i. e. relaxation methods) have also been used in mechanistic studies, increasingly so in recent years. This topic is discussed in detail by Professor K. Tamaru in Chapter 2. At a deeper level of understanding, one may seek to