弄碎 发表于 2025-3-21 16:32:42

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Jargon 发表于 2025-3-21 23:39:15

https://doi.org/10.1007/978-0-387-92265-2Carbohydrate; Chemistry; Glycoscience; Miljkovic; Natural products; Oxidation; Reaction mechanisms; natural

CRP743 发表于 2025-3-22 02:38:29

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Deceit 发表于 2025-3-22 07:56:53

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ARM 发表于 2025-3-22 12:46:07

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Osteoarthritis 发表于 2025-3-22 13:45:06

Nucleophilic Displacement and the Neighboring Group Participation,nal bipyramidal pentacovalent carbon transition state . and results in the inversion of configuration at the reacting carbon atom (the configuration of . vs. .) (Fig. 7.1); it usually follows the second-order kinetics.

Osteoarthritis 发表于 2025-3-22 18:21:51

Oxidation of Monosaccharides,vatives from simple monosaccharides. As already mentioned in Chapter 5 the carbohydrates have three types of chemically distinct hydroxyl groups: (1) the primary hydroxyl groups which are always exocyclic and (2) two types of secondary hydroxyl groups: endo- and exocyclic hydroxyl groups.

ENACT 发表于 2025-3-22 23:11:02

Synthesis of Polychiral Natural Products from Carbohydrates,s of macrolide antibiotics represents one such difficult problem. They consist of macrocyclic lactone rings with many hydroxylated and methylated chiral carbons. In addition to that the macrocyclic lactones (macrolides) are usually glycosylated with amino sugars.

Intractable 发表于 2025-3-23 04:26:07

pplementary material: .All essential areas of basic synthetic carbohydrate chemistry are covered and appropriately described. In addition, this book explains the basic reaction mechanisms while taking into account modern concepts such as stereoelectronic principles..978-1-4614-9825-4978-0-387-92265-2

PALSY 发表于 2025-3-23 09:33:16

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查看完整版本: Titlebook: Carbohydrates; Synthesis, Mechanism Momcilo Miljkovic Book 2009 Springer-Verlag New York 2009 Carbohydrate.Chemistry.Glycoscience.Miljkovic