DUMMY
发表于 2025-3-21 16:30:51
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Bureaucracy
发表于 2025-3-21 20:14:02
The Site Factor, between the centres of mass. In NMR, where measurements are done on nuclei (.H, .F) which are usually on the periphery of the molecules such assumption seems not too well warranted; a fact recognized, but still neglected in the early work of Bothner-By [.] and of others after him [.].
安定
发表于 2025-3-22 00:54:53
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surmount
发表于 2025-3-22 05:57:05
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BRIDE
发表于 2025-3-22 11:32:19
Factor Analysis,ntribuant; σ.. At the same time it is clear that our preoccupation with σ. has as one of its goals the development of a model for σ. which allows us to . σ. with good confidence in those systems where the medium shift is composed of two or more terms. Factor analysis therefore seems to provide an alternative way of separating these effects.
indoctrinate
发表于 2025-3-22 13:38:49
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adduction
发表于 2025-3-22 17:44:02
,Pair Interaction Models for σw, the molar volume of the medium (tobe averaged on a mole fraction basis in case of mixtures), σ. is the 2. virial coefficient of corresponding to . collisions while σ., σ.... correspond to ternary and higher order collisions.
学术讨论会
发表于 2025-3-22 21:19:57
The Parameters ,,th . where some model for . has been inserted. With such a “simulated” field one then arrives at “simulated” . parameters. Such calculations have also been included in the present chapter. Therefore the material of this chapter will allow a comparison between the effective electric field theories and the direct interactive theories for σ..
crease
发表于 2025-3-23 02:19:45
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较早
发表于 2025-3-23 07:39:40
,σw of Nuclei other than 1H and 19 F, In subsequent paper [.] several more of such data were given, but a full discussion of the .C, .Si and .H solvent effects of TMS and cyclohexane by Bacon and Maciel [.] includes all previous data. In Table 41 all the relevant data . pertaining to pure σ. effects only) is given.