Electrolysis
发表于 2025-3-23 10:18:47
Ultrafast Electron and Proton Reactivity in Molecular Liquids,he elementary steps of a reaction often correspond to very short lived transitional states between reactants and products [.–.]. At the molecular level, the lifetime of transient steps (. ≤ 10. s) correspond to angström or subangström displacements.
organism
发表于 2025-3-23 17:30:27
The Dynamics of Anion Solvation in Alcohols,ay was not possible. These roles include: supplying or dissipating energy by acting as a heat bath, confining reactants, and solvation of ions. Solvation will be important for any reactions in which charge is created, destroyed or transferred, including intra-molecular charge redistribution, which,
AGGER
发表于 2025-3-23 22:06:15
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Enteropathic
发表于 2025-3-23 23:32:53
Ultrafast Transient Raman Investigations of Condensed Phase Dynamics,to be painstakingly built from scratch in the laboratory. Today, much better lasers are available commercially. State-of-the-art titanium sapphire lasers routinely generate 100 fs pulses. Amplification to millijoule pulses at repetition rates of 1 kHz (and microjuole pulses at 250 kHz) is now routin
thalamus
发表于 2025-3-24 03:13:39
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Allure
发表于 2025-3-24 08:16:26
The Molecular Basis of Solvent Caging,f gas phase reactions has reached a high level of sophistication, many open questions remain concerning reactivity in the liquid phase. Reactant species suffer 10. collisions per second in a room temperature solvent. These collisions can cause energy exchange between the solvent and the reactant, pe
轨道
发表于 2025-3-24 10:47:58
Dielectric Continuum Models of Solute/Solvent Interactions,the case of chemical reactions, polarity effects of the medium can significantly alter reaction rates and the relative yields of different reaction products. However these interactions are not quantitatively understood for molecular systems. This failing is clearly indicated by the prevalence of sem
晚间
发表于 2025-3-24 15:58:20
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极大痛苦
发表于 2025-3-24 19:55:46
Chemistry in Clusters: Solvation at the Single Molecule Level,mewhere in between. If so, then it is reasonable to expect that the physical and chemical behavior of clusters should take on properties that are intermediate between gas phase and condensed phase properties. The impetus to cluster research is driven largely by the potential to learn about the corre
Incumbent
发表于 2025-3-25 03:13:01
Charge Transfer Reactions and Solvation Dynamics,t of heavy particle charge transfer reactions. These reactions include S.2 nucleophilic displacements — .. + . → . + .. S.1 unimolecular ionizations —. →, .. + dipolar isomerizations, and (with a certain elasticity of definition) ion pair interconversion. Here the solvation dynamics act to influence